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(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

CAS号：682352-09-6

英文名：(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

分子式：C20H28O3S

分子量：348.5

合成路线

(1S,2R,5R,7S,9R)-5-propionyl-10,10-dimethyl-4-oxa-6-thiatricyclo[7.1.1.02,7]undecane

(1S,2R,5R,7S,9R)-5-propionyl-10,10-dimethyl-4-oxa-6-thiatricyclo[7.1.1.02,7]undecane

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

(1S,2R,5R,7S,9R,1'R)-5-(1'-hydroxy-1'-phenyl-1'-propyl)-10,10-dimethyl-4-oxa-6-thia-tricyclo[7.1.1.02,7]undecane

(1S,2R,5R,7S,9R,1'R)-5-(1'-hydroxy-1'-phenyl-1'-propyl)-10,10-dimethyl-4-oxa-6-thia-tricyclo[7.1.1.02,7]undecane

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

(1S,2R,6S)-9,9-dimethyl-4-oxa-5-thiatricyclo[6.1.1.02,6]decane 5-oxide

(1S,2R,6S)-9,9-dimethyl-4-oxa-5-thiatricyclo[6.1.1.02,6]decane 5-oxide

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

(1S,2R,3S,5R,2'R)-6,6-dimethyl-3-(2'-ethoxy-1'-phenyl-1'-oxo-2'-ethylsulfanyl)-2-hydroxymethyl-bicyclo[3.1.1]heptane

上游原料

(1S,2R,5R,7S,9R,1'R)-5-(1'-hydroxy-1'-phenyl-1'-propyl)-10,10-dimethyl-4-oxa-6-thia-tricyclo[7.1.1.02,7]undecane (1S,2R,5R,7S,9R)-5-propionyl-10,10-dimethyl-4-oxa-6-thiatricyclo[7.1.1.02,7]undecane (1S,2R,6S)-9,9-dimethyl-4-oxa-5-thiatricyclo[6.1.1.02,6]decane 5-oxide

下游产品

(S)-2-羟基-2-苯基丁酸 (S)-(+)-2-羟基-2-苯丙酸 (1R,2S)-1-[(1S,2R,3S,5R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6,6-dimethyl-bicyclo[3.1.1]hept-3-ylsulfanyl]-1-ethoxy-2-phenyl-but-3-en-2-ol (2S)-2-Phenyl-1,4-butanediol