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(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

CAS号：682744-26-9

英文名：(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

分子式：C41H55ClO4Si

分子量：675.411

合成路线

765950-74-1

Formic acid 3,4-bis-benzyloxy-5-chloro-phenyl ester

682744-26-9

(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

765950-76-3

1,2-dibenzyloxy-3-chloro-5-(tert-butyldimethylsilyloxy)benzene

682744-26-9

(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

682744-25-8

4-bromo-3-chloro-1,2-dibenzyloxy-5-(tert-butyldimethylsilyloxy)benzene

155551-30-7

(1S,4aS,8aS)-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

682744-26-9

(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

765950-75-2

3,4-dibenzyloxy-5-chlorophenol

682744-26-9

(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

765950-72-9

(3aR,5aS,9aS,9bR)-dodecahydro-3a,6,6,9a,-tetramethylnaphtho-[2,1-b]furan-1,2-diol

682744-26-9

(1S,4aS,8aS)-1-[(3,4-dibenzyloxy-6-tert-butyldimethylsilyloxy-2-chlorophenyl)-hydroxymethyl]-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene

上游原料

1,2-dibenzyloxy-3-chloro-5-(tert-butyldimethylsilyloxy)benzene (3aR,5aS,9aS,9bR)-dodecahydro-3a,6,6,9a,-tetramethylnaphtho-[2,1-b]furan-1,2-diol Formic acid 3,4-bis-benzyloxy-5-chloro-phenyl ester 3,4-dibenzyloxy-5-chlorophenol (1S,4aS,8aS)-3H-2-methylene-1,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalene-1-carboxaldehyde 4-bromo-3-chloro-1,2-dibenzyloxy-5-(tert-butyldimethylsilyloxy)benzene

下游产品

(4aS,6aS,12bS)-2H-9,10-dibenzyloxy-11-chloro-1,3,4,4a,5,6,6a,12b-octahydro-4,4,6a,12b-tetramethyl-benzo[a]xanthene (4aS,6aS,12bS)-2H-9,10-dibenzyloxy-11-chloro-1,3,4,4a,5,6,6a,12b-octahydro-6a-[(phenylseleno)methyl]-4,4,12b-trimethyl-benzo[a]xanthene (4aS,6aS,12aR,12bS)-2H-11-chloro-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-4,4,6a,12b-tetramethyl-benzo[a]xanthene-9,10-diol