百科

(3Z,9E)-(1R,7S,11S,17R)-11-(tert-butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-13-methylidene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

(3Z,9E)-(1R,7S,11S,17R)-11-(tert-butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-13-methylidene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

CAS号：688743-60-4

英文名：(3Z,9E)-(1R,7S,11S,17R)-11-(tert-butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-13-methylidene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

分子式：C43H62O5Si2

分子量：715.12

合成路线

(3Z,9E,14E)-(1R,7S,11S,17S)-11-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,14,19-tetraene-5,13-dione

(3Z,9E,14E)-(1R,7S,11S,17S)-11-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,14,19-tetraene-5,13-dione

(3Z,9E)-(1R,7S,11S,17R)-11-(tert-butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-13-methylidene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

(3Z,9E)-(1R,7S,11S,17R)-11-(tert-butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-13-methylidene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

上游原料

(3Z,9E,14E)-(1R,7S,11S,17S)-11-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,14,19-tetraene-5,13-dione

下游产品

(3Z,9E)-(1R,7S,11S,17R)-11-(tert-butyl-dimethyl-silanyloxy)-13-methylidene-5-oxo-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-7-carbaldehyde (3Z,9E)-(1R,7S,11S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one (3Z,9E)-(1R,7S,11S,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-methoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one