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(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol

(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol

CAS号：692734-51-3
英文名：(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
分子式：C55H102O7Si4
分子量：987.736
合成路线
5-((S)-2-methylpentane-1-sulfonyl)-1-phenyl-1H-tetrazole
868057-10-7
5-((S)-2-methylpentane-1-sulfonyl)-1-phenyl-1H-tetrazole
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
(2R,3S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-1-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-pentan-1-one
868056-88-6
(2R,3S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-1-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-pentan-1-one
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
{(2R,3S)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1,4-dioxa-spiro[4.4]non-2-yl}-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-methanone
692734-45-5
{(2R,3S)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1,4-dioxa-spiro[4.4]non-2-yl}-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-methanone
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
(2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-6-trimethylsilanyl-hex-5-ynal
692734-59-1
(2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-6-trimethylsilanyl-hex-5-ynal
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
(2S,3R)-3-[1-((2S,3S)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]nonane-2-carbaldehyde
692734-67-1
(2S,3R)-3-[1-((2S,3S)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]nonane-2-carbaldehyde
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
{(2R,3R)-3-[1-((2S,3S)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-methanol
692734-46-6
{(2R,3R)-3-[1-((2S,3S)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-methanol
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
((2S,3S)-3-{1-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-acetaldehyde
692734-66-0
((2S,3S)-3-{1-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-acetaldehyde
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
(2R,3R)-2-(1-((2S,3S)-3-allyl-1,4-dioxaspiro[4.4]nonan-2-yl)vinyl)-3-(((4-methoxybenzyl)oxy)methyl)-1,4-dioxaspiro[4.4]nonane
692734-56-8
(2R,3R)-2-(1-((2S,3S)-3-allyl-1,4-dioxaspiro[4.4]nonan-2-yl)vinyl)-3-(((4-methoxybenzyl)oxy)methyl)-1,4-dioxaspiro[4.4]nonane
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
2-((2S,3S)-3-{1-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-ethanol
692734-55-7
2-((2S,3S)-3-{1-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-ethanol
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
tert-butyl(2-{(2S,3S)-3-[1-((2R,3R)-3-{[(4-methoxybenzyl)oxy]methyl}-1,4-dioxaspiro[4.4]non-2-yl)vinyl]-1,4-dioxaspiro[4.4]non-2-yl}ethoxy)dimethylsilane
692734-54-6
tert-butyl(2-{(2S,3S)-3-[1-((2R,3R)-3-{[(4-methoxybenzyl)oxy]methyl}-1,4-dioxaspiro[4.4]non-2-yl)vinyl]-1,4-dioxaspiro[4.4]non-2-yl}ethoxy)dimethylsilane
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
692734-51-3
(5S)-4,5-anhydro-1,2-dideoxy-3-O-{(2E,4E,8R,9R,11S,12S)-3-methyl-7,10-bis(methylene)-8,9,11,12-tetrakis[(triethylsilyl)oxy]pentadeca-2,4,14-trienoyl}-5-[(1S)-1-methylbutyl]-2-prop-2-yn-1-yl-D-ribitol
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上游原料
(E)-(4R,5S,8S)-4,8-Dimethyl-undec-6-en-1-yn-5-ol ((2S,3S)-3-{1-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-acetaldehyde (2R,3S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-1-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-pentan-1-one (E)-(4R,5S,8S)-5-(tert-Butyl-dimethyl-silanyloxy)-4,8-dimethyl-1-trimethylsilanyl-undec-6-en-1-yne (E)-5-(tert-Butyl-dimethyl-silanyloxy)-1-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-pent-2-en-1-one (E)-(R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-[(2R,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-pent-2-en-1-ol (2S,3R)-3-[1-((2S,3S)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]nonane-2-carbaldehyde {(2R,3R)-3-[1-((2S,3S)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-methanol 2-((2S,3S)-3-{1-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-ethanol (R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-[(2R,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-pent-2-yn-1-ol {(2R,3S)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1,4-dioxa-spiro[4.4]non-2-yl}-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-methanone (2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-6-trimethylsilanyl-hex-5-ynal tert-butyl(2-{(2S,3S)-3-[1-((2R,3R)-3-{[(4-methoxybenzyl)oxy]methyl}-1,4-dioxaspiro[4.4]non-2-yl)vinyl]-1,4-dioxaspiro[4.4]non-2-yl}ethoxy)dimethylsilane (2R,3R)-2-(1-((2S,3S)-3-allyl-1,4-dioxaspiro[4.4]nonan-2-yl)vinyl)-3-(((4-methoxybenzyl)oxy)methyl)-1,4-dioxaspiro[4.4]nonane 5-((S)-2-methylpentane-1-sulfonyl)-1-phenyl-1H-tetrazole
下游产品
(5S)-4,5-anhydro-1,2-dideoxy-5-[(1R)-1-methylbutyl]-2-prop-2-yn-1-yl-3-O-[(2E,4E,8R,9R,11S,12S)-8,9,11,12-tetrahydroxy-3-methyl-7,10-bis(methylene)pentadeca-2,4,14-trienoyl]-D-ribitol
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