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(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

CAS号：692749-45-4

英文名：(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

分子式：C19H31NO5

分子量：353.453

合成路线

(E)-(2R,3S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-4-enal

(E)-(2R,3S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-4-enal

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

(6E,9Z)-(2S,3R,4S,5S,8S)-1,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-((S)-3-ethyl-4,5-dihydro-isoxazol-5-yl)-6,8-dimethyl-undeca-6,9-dien-3-ol

(6E,9Z)-(2S,3R,4S,5S,8S)-1,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-((S)-3-ethyl-4,5-dihydro-isoxazol-5-yl)-6,8-dimethyl-undeca-6,9-dien-3-ol

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

(E)-(R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-pent-2-en-1-ol

(E)-(R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-pent-2-en-1-ol

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

(6E,9Z)-(2R,4R,5S,8S)-2-((S)-3-Ethyl-4,5-dihydro-isoxazol-5-yl)-1,5-dihydroxy-4-hydroxymethyl-6,8-dimethyl-undeca-6,9-dien-3-one

上游原料

(E)-(2R,3S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-4-enal (E)-(R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-pent-2-en-1-ol (6E,9Z)-(2S,3R,4S,5S,8S)-1,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-((S)-3-ethyl-4,5-dihydro-isoxazol-5-yl)-6,8-dimethyl-undeca-6,9-dien-3-ol

下游产品

(1S,2R,4R,5S)-2,4-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,5-dihydroxy-1-[(2R,3R)-2-methyl-3-((Z)-(S)-1-methyl-but-2-enyl)-oxiranyl]-nonane-3,7-dione (10E,13Z)-(5S,6R,8R,9S,12S)-6,8-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-5,9-dihydroxy-10,12-dimethyl-pentadeca-10,13-diene-3,7-dione