百科

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

CAS号：693239-30-4

英文名：3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

分子式：C24H36O7

分子量：436.538

合成路线

(3aS,4aR,8aS,10R,10aS)-10-Ethynyl-2,2-dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulene

(3aS,4aR,8aS,10R,10aS)-10-Ethynyl-2,2-dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulene

(2S,3R,4aR,8aS)-3-Methyl-octahydro-pyrano[3,2-b]pyran-2-carbaldehyde

(2S,3R,4aR,8aS)-3-Methyl-octahydro-pyrano[3,2-b]pyran-2-carbaldehyde

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

(2S,4aR,8aS)-2-Benzyloxymethyl-3-methylene-octahydro-pyrano[3,2-b]pyran

(2S,4aR,8aS)-2-Benzyloxymethyl-3-methylene-octahydro-pyrano[3,2-b]pyran

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

(3aS,4aR,8aS,10R,10aS)-10-(2,2-Dibromo-vinyl)-2,2-dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulene

(3aS,4aR,8aS,10R,10aS)-10-(2,2-Dibromo-vinyl)-2,2-dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulene

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

3-((3aS,4aR,8aS,10R,10aS)-2,2-Dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulen-10-yl)-1-((2S,3R,4aR,8aS)-3-methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-yn-1-ol

上游原料

(2S,3R,4aR,8aS)-3-Methyl-octahydro-pyrano[3,2-b]pyran-2-carbaldehyde (3aS,4aR,8aS,10R,10aS)-10-(2,2-Dibromo-vinyl)-2,2-dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulene (3aS,4aR,8aS,10R,10aS)-10-Ethynyl-2,2-dimethyl-octahydro-1,3,5,9-tetraoxa-benzo[f]azulene (2S,4aR,8aS)-2-Benzyloxymethyl-3-methylene-octahydro-pyrano[3,2-b]pyran

下游产品

(4aS,5aR,8S,9aS,10S,11aR)-8-((2S,3R,4aR,8aS)-3-Methyl-octahydro-pyrano[3,2-b]pyran-2-yl)-dodecahydro-1,5,9-trioxa-dibenzo[a,d]cyclohepten-10-ol