百科

Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

CAS号：71387-31-0

英文名：Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

分子式：C30H47NO2

分子量：453.7

合成路线

3β-tetrahydropyranyloxy-22,23-bisnorchol-5-en-24-al-24-(1,3-dithiane-2-)acetal

3β-tetrahydropyranyloxy-22,23-bisnorchol-5-en-24-al-24-(1,3-dithiane-2-)acetal

Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

3-((10R,13R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-butyraldehyde

3-((10R,13R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-butyraldehyde

Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

Acetic acid (3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-((E)-(S)-1-methyl-3-piperidin-1-yl-allyl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

上游原料

3β-tetrahydropyranyloxy-22,23-bisnorchol-5-en-24-al-24-(1,3-dithiane-2-)acetal 3-((10R,13R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-butyraldehyde

下游产品

<22S>-3β-acetoxy-22-methanesulfonyloxymethyl-chol-5-en-24-al <22S>-22-methanesulfonyloxymethyl-26,27-bisnorcholesta-5,24-dien-3β-ol 3-acetate 22-hydroxymethyl-23-methyl-26,27-bisnorcholesta-5,24-dien-3β-ol 3-acetate <22R,23S,24R and S>-22,23-methano-cholest-5-en-3β,24-diol 3-acetate <22R>-22-hydroxymethyl-26,27-bisnorcholesta-5,24-dien-3β-ol 3-acetate Acetic acid (3S,8S,9S,10R,13R,14S,17R)-17-((1S,2R)-2-methanesulfonyloxymethyl-1-methyl-4-oxo-butyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester Acetic acid (3S,8S,9S,10R,13R,14S,17R)-17-((1S,2R)-4,5-dihydroxy-2-methanesulfonyloxymethyl-1-methyl-pentyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester Acetic acid (3S,8S,9S,10R,13R,14S,17R)-17-((1S,2R)-2-methanesulfonyloxymethyl-1-methyl-pent-4-enyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester