百科

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

CAS号：720678-41-1

英文名：(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

分子式：C42H76O10Si

分子量：769.132

合成路线

(4R,5R)-1-iodo-4,5-isopropylidenedioxy-14-pentadecene

(4R,5R)-1-iodo-4,5-isopropylidenedioxy-14-pentadecene

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9S,12R,13R)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricos-22-en-1,4-olide

(4R,5R,8R,9S,12R,13R)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricos-22-en-1,4-olide

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(cis,4R,5R,12R,13R)-5-tert-butyldiphenylsilyloxytricos-12,13-isopropylidenedioxy-8,22-dien-1,4-olide

(cis,4R,5R,12R,13R)-5-tert-butyldiphenylsilyloxytricos-12,13-isopropylidenedioxy-8,22-dien-1,4-olide

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9S,12R,13R)-12,13-dihydroxy-9-mesyloxy-5,8-oxidotricos-22-en-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-dihydroxy-9-mesyloxy-5,8-oxidotricos-22-en-1,4-olide

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

(4R,5R,8R,9R,12R,13R)-1-tert-butyldimethylsilyloxy-4,13-di(methoxymethoxy)-23-(p-methoxybenzyloxy)methoxy-5,8,9,12-dioxidotricosane

上游原料

(4R,5R,8R,9S,12R,13R)-12,13-dihydroxy-9-mesyloxy-5,8-oxidotricos-22-en-1,4-olide (4R,5R,8R,9S,12R,13R)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricos-22-en-1,4-olide (cis,4R,5R,12R,13R)-5-tert-butyldiphenylsilyloxytricos-12,13-isopropylidenedioxy-8,22-dien-1,4-olide (4R,5R)-1-iodo-4,5-isopropylidenedioxy-14-pentadecene

下游产品

4-tert-butyldimethylsilyloxy-15,24-di(methoxymethoxy)-34-hydroxyasimicin 4-tert-butyldimethylsilyloxy-15,24-di(methoxymethoxy)-34-(p-methoxybenzyloxymethyloxy)asimicin {(E,Z)}-4-tert-butyldimethylsilyloxy-15,24-di(methoxymethoxy)-34-(p-methoxybenzyloxy)methyloxyasimicin-9-en-11-yne