百科

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

CAS号：72397-63-8

英文名：(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

分子式：C14H24O2Si

分子量：252.425

合成路线

6-Bromo-5-(tert-butyl-dimethyl-silanyloxy)-hexahydro-pentalen-1-one

6-Bromo-5-(tert-butyl-dimethyl-silanyloxy)-hexahydro-pentalen-1-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

6-Bromo-5-hydroxy-hexahydro-pentalen-1-one

6-Bromo-5-hydroxy-hexahydro-pentalen-1-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

82653-88-1

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

82653-89-2

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

(5RS,7SR)-7-t-butyldimethylsilyloxybicyclo[3.3.0]oct-8-en-2-one

上游原料

6-Bromo-5-hydroxy-hexahydro-pentalen-1-one 6-Bromo-5-(tert-butyl-dimethyl-silanyloxy)-hexahydro-pentalen-1-one

下游产品

5-[(3aS,4S,5S,6aR)-5-Hydroxy-4-((E)-3-hydroxy-oct-1-enyl)-1,3a,4,5,6,6a-hexahydro-pentalen-2-yl]-pentanoic acid methyl ester methyl (1S*,5S*,7R*,8R*)-7-tert-butyldimethylsilyloxy-3-methoxycarbonyl-8-(3-tert-butyldimethylsilyloxy-E-1-octenyl)-2-oxobicyclo<3.3.0>octane-3-pentanoate methyl (1S*,5S*,7R*,8R*)-7-tert-butyldimethylsilyloxy-8-(3-tert-butyldimethylsilyloxy-E-1-octenyl)-2-oxobicyclo<3.3.0>octane-3-carboxylate (1RS,2SR,5RS,7SR,8SR)-7-t-butyldimethylsilyloxy-3,3,8-trimethylbicyclo<3.3.0>octan-2-ol (1R,2R,7S,8S,11R)-7,11-diacetoxy-2,10,10-trimethyl-3-methylenetricyclo<6,3,0,02,6>undec-5-en-4-one 7-endo-hydroxybicyclo<3.3.0>oct-8-en-2-one