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(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

CAS号：726192-15-0

英文名：(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

分子式：C14H21NO5

分子量：283.32

合成路线

(1S,3S,4R,4'R,5'R)-tert-butyl 4',5'-diphenyl-3-(phenylsulfonyl)-7-azaspiro[bicyclo[2.2.1]hept[5]ene-2,2'-[1,3]dioxolane]-7-carboxylate

(1S,3S,4R,4'R,5'R)-tert-butyl 4',5'-diphenyl-3-(phenylsulfonyl)-7-azaspiro[bicyclo[2.2.1]hept[5]ene-2,2'-[1,3]dioxolane]-7-carboxylate

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

(+)-(1R,2S,3R,4S,5R,6S)-7-tert-butoxycarbonyl-2,3-exo-isopropylidenedioxy-6-endo-p-toluenesulfonyl-7-azabicyclo[2.2.1]heptane-5-endo-ol

(+)-(1R,2S,3R,4S,5R,6S)-7-tert-butoxycarbonyl-2,3-exo-isopropylidenedioxy-6-endo-p-toluenesulfonyl-7-azabicyclo[2.2.1]heptane-5-endo-ol

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

(1R,2R,3S,4S,4'R,5'R)-4',5'-diphenylspiro[2,3-exo-isopropylidenedioxy-7-tert-butoxycarbonyl-7-azabicyclo[2.2.1]hept-2,2'-imidazoline]

(1R,2R,3S,4S,4'R,5'R)-4',5'-diphenylspiro[2,3-exo-isopropylidenedioxy-7-tert-butoxycarbonyl-7-azabicyclo[2.2.1]hept-2,2'-imidazoline]

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

(3aR,4S,7S,7aS)-tert-butyl 2,2-dimethyl-5-oxohexahydro-4,7-epiminobenzo[d][1,3]dioxole-8-carboxylate

上游原料

(1S,3S,4R,4'R,5'R)-tert-butyl 4',5'-diphenyl-3-(phenylsulfonyl)-7-azaspiro[bicyclo[2.2.1]hept[5]ene-2,2'-[1,3]dioxolane]-7-carboxylate (1R,2R,3S,4S,4'R,5'R)-4',5'-diphenylspiro[2,3-exo-isopropylidenedioxy-7-tert-butoxycarbonyl-7-azabicyclo[2.2.1]hept-2,2'-imidazoline] (+)-(1R,2S,3R,4S,5R,6S)-7-tert-butoxycarbonyl-2,3-exo-isopropylidenedioxy-6-endo-p-toluenesulfonyl-7-azabicyclo[2.2.1]heptane-5-endo-ol

下游产品

(3aR,4S,6S,6aS)-4-(Benzyloxycarbonylmethyl-carbamoyl)-6-hydroxymethyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid tert-butyl ester {[(3aR,4S,6S,6aS)-5-((S)-2-tert-Butoxycarbonylamino-3-phenyl-propionyl)-6-hydroxymethyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-4-carbonyl]-amino}-acetic acid benzyl ester