百科

(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

CAS号：729596-21-8

英文名：(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

分子式：C19H24O10S

分子量：444.453

合成路线

ethyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glycero-L-ido-heptofuranuronate

ethyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glycero-L-ido-heptofuranuronate

(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

ethyl (E)-[3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-gluco]-heptofuran-5-en-uronate

ethyl (E)-[3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-gluco]-heptofuran-5-en-uronate

(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

(4S,5R)-5-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2,2-dioxo-2λ6-[1,3,2]dioxathiolane-4-carboxylic acid ethyl ester

上游原料

ethyl (E)-[3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-gluco]-heptofuran-5-en-uronate ethyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glycero-L-ido-heptofuranuronate

下游产品

3,5,7-tri-O-acetyl-6-(N-benzyloxycarbonylamino)-6-deoxy-1,2-O-isopropylidene-β-L-glycero-L-ido-heptofuranose ethyl 6-azido-6-deoxy-3-O-benzyl-1,2-O-isopropylidene-β-L-glycero-L-ido-heptofuranuronate 6-benzyloxycarbonylamino-6-deoxy-1,2-O-isopropylidene-β-L-glycero-L-ido-hepto-1,4-furanose