百科

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

CAS号：73992-06-0

英文名：(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

分子式：C16H27IO4

分子量：410.288

合成路线

(Z)-(2R,4S,8S)-8-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,4-dimethyl-non-5-enoic acid

(Z)-(2R,4S,8S)-8-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,4-dimethyl-non-5-enoic acid

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(S)-3-methyl-4-pentenoic acid benzyl ester

(S)-3-methyl-4-pentenoic acid benzyl ester

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(S)-(+)-3-methyl-4-pentenoic acid

(S)-(+)-3-methyl-4-pentenoic acid

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(4S,5S)-5-Iodomethyl-4-methyl-dihydro-furan-2-one

(4S,5S)-5-Iodomethyl-4-methyl-dihydro-furan-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(4S,5R)-dihydro-5-hydroxymethyl-4-methyl-2(3H)-furanone

(4S,5R)-dihydro-5-hydroxymethyl-4-methyl-2(3H)-furanone

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(S,Z)-methyl 5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-2-enoate

(S,Z)-methyl 5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-2-enoate

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

((2S,4R)-4-Carboxy-2-methyl-pentyl)-triphenyl-phosphonium; iodide

((2S,4R)-4-Carboxy-2-methyl-pentyl)-triphenyl-phosphonium; iodide

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

(3R,5S,6S)-6-[(1S,3S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-iodo-butyl]-3,5-dimethyl-tetrahydro-pyran-2-one

上游原料

(S)-3-methyl-4-pentenoic acid benzyl ester (4S,5R)-dihydro-5-hydroxymethyl-4-methyl-2(3H)-furanone (S)-(+)-3-methyl-4-pentenoic acid ((2S,4R)-4-Carboxy-2-methyl-pentyl)-triphenyl-phosphonium; iodide (4S,5S)-5-Iodomethyl-4-methyl-dihydro-furan-2-one (Z)-(2R,4S,8S)-8-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,4-dimethyl-non-5-enoic acid (S,Z)-methyl 5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-2-enoate

下游产品

(2R,3S,5R)-5-((2S,3S,5R)-3,5-Dimethyl-6-oxo-tetrahydro-pyran-2-yl)-3-methyl-tetrahydro-furan-2-carbothioic acid S-pyridin-2-yl ester (3R,5S,6S)-6-((2R,4S,5R)-5-Hydroxymethyl-4-methyl-tetrahydro-furan-2-yl)-3,5-dimethyl-tetrahydro-pyran-2-one