百科

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

CAS号：744261-13-0

英文名：(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

分子式：C26H48O2Si

分子量：420.744

合成路线

(4aS,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-5-(4-methylpent-3-enyl)decahydronaphthalen-1-one

(4aS,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-5-(4-methylpent-3-enyl)decahydronaphthalen-1-one

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(4aR,5S,6S,8aR)-6-(tert-butyldimethylsilyloxy)-2-(tri-n-butylstannylmethoxymethyl)-5,8a-dimethyl-5-(4-methylpent-3-enyl)-3,,4,4a,5,6,7,8,8a-octahhydronaphthalene

(4aR,5S,6S,8aR)-6-(tert-butyldimethylsilyloxy)-2-(tri-n-butylstannylmethoxymethyl)-5,8a-dimethyl-5-(4-methylpent-3-enyl)-3,,4,4a,5,6,7,8,8a-octahhydronaphthalene

(4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-2-methoxymethyl-5,8a-dimethyl-5-(4-methylpent-3-enyl)-3,4,4a,5,6,7,8,8a-octahydronaphthalene

(4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-2-methoxymethyl-5,8a-dimethyl-5-(4-methylpent-3-enyl)-3,4,4a,5,6,7,8,8a-octahydronaphthalene

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(4aS,5S,6S,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one-1-ethylene acetal

(4aS,5S,6S,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one-1-ethylene acetal

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(4aS,5S,6S,8aS)-(-)-2,4,4a,5,6,7,8,8a-Octahydro-6-hydroxy-5,8a-dimethyl-5-(prop-2-enyl)naphthalen-1(2H)-one 1-(Ethylene Acetal)

(4aS,5S,6S,8aS)-(-)-2,4,4a,5,6,7,8,8a-Octahydro-6-hydroxy-5,8a-dimethyl-5-(prop-2-enyl)naphthalen-1(2H)-one 1-(Ethylene Acetal)

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

(1R,4aR,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-2-methylene-5-(4-methylpent-3-enyl)-decahydronaphthalene-1-methanol

上游原料

(4aS,5S,6S,8aS)-6-(tert-butyldimethylsiloxy)-5,8a-dimethyl-5-(4-methylpent-3-enyl)decahydronaphthalen-1-one (4aS,5S,6S,8aS)-5,8a-dimethyl-6-hydroxy-5-(3-hydroxypropyl)decahydronaphthalen-1-one-1-ethylene acetal (4aR,5S,6S,8aR)-6-(tert-butyldimethylsilyloxy)-2-(tri-n-butylstannylmethoxymethyl)-5,8a-dimethyl-5-(4-methylpent-3-enyl)-3,,4,4a,5,6,7,8,8a-octahhydronaphthalene (4aS,5S,6S,8aS)-(-)-2,4,4a,5,6,7,8,8a-Octahydro-6-hydroxy-5,8a-dimethyl-5-(prop-2-enyl)naphthalen-1(2H)-one 1-(Ethylene Acetal)

下游产品

Dithiocarbonic acid O-[[(1R,4aR,5S,6S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5,8a-dimethyl-2-methylene-5-(4-methyl-pent-3-enyl)-decahydro-naphthalen-1-yl]-(2-methoxy-5,6-dimethyl-4-oxo-4H-pyran-3-yl)-methyl] ester S-methyl ester