百科

(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

CAS号：745032-78-4

英文名：(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

分子式：C17H22O4S

分子量：322.419

合成路线

(1R,4R,5R)-4-(phenylthio)-6,8-dioxabicyclo[3.2.1]octan-2-one

(1R,4R,5R)-4-(phenylthio)-6,8-dioxabicyclo[3.2.1]octan-2-one

(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

(1R,2S,4R,5R)-4-(phenylthio)-6,8-dioxabicyclo[3.2.1]octan-2-ol

(1R,2S,4R,5R)-4-(phenylthio)-6,8-dioxabicyclo[3.2.1]octan-2-ol

(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

(2R,3S,5R,6S)-3-(acetyloxy)-tetrahydro-5-(phenylthio)-6-(prop-2-enyl)-2H-pyran-2-methanol

上游原料

(1R,2S,4R,5R)-4-(phenylthio)-6,8-dioxabicyclo[3.2.1]octan-2-ol (1R,4R,5R)-4-(phenylthio)-6,8-dioxabicyclo[3.2.1]octan-2-one

下游产品

(2R,5R,6S)-5,6-dihydro-2-[(methoxymethoxy)methyl]-5-(phenylthio)-6-{(2Z)-4-[(2S,3R,4R,5R,6S)-tetrahydro-3,4,5-tris(methoxymethoxy)-6-methyl-2H-pyran-2yl]but-2-enyl}-2H-pyran-3(4H)-one (2R,3S,6S)-tetrahydro-2-[(methoxymethoxy)methyl]-6-{4-[(2S,3R,4R,5R,6S)-tetrahydro-3,4,5-tris(methoxymethoxy)-6-methyl-2H-pyran-2-yl]butyl}-2H-pyran-3-ol (2R,3S,5R,6S)-tetrahydro-2-[(methoxymethoxy)methyl]-5-(phenylthio)-6-{(2Z)-4-[(2S,3R,4R,5R,6S)-tetrahydro-3,4,5-tris(methoxymethoxy)-6-methyl-2H-pyran-2-yl]but-2-enyl}-2H-pyran-3-ol (2R,3S,5R,6S)-tetrahydro-2-[(methoxymethoxy)methyl]-5-(phenylthio)-6{(2Z)-4-[(2S,3R,4R,5R,6S)-tetrahydro-3,4,5-tris(methoxymethoxy)-6-methyl-2H-pyran-2yl]but-2-enyl}-2H-pyran-3-ol acetate (2S,3R,5S,6R)-5-(acetyloxy)-tetrahydro-6-[(methoxymethyl)methyl]-3-(phenylthio)-2H-pyran-2-acetaldehyde