百科

(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

CAS号：75858-29-6

英文名：(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

分子式：C26H32O6

分子量：440.529

合成路线

2,3-di-O-benzyl-4,5-O-isopropylidene-aldehydo-L-arabinose

2,3-di-O-benzyl-4,5-O-isopropylidene-aldehydo-L-arabinose

(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

2,3-di-O-benzyl-4,5-O-isopropylidene-L-arabinose di(ethylthio)acetal

2,3-di-O-benzyl-4,5-O-isopropylidene-L-arabinose di(ethylthio)acetal

(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

(E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

上游原料

2,3-di-O-benzyl-4,5-O-isopropylidene-aldehydo-L-arabinose 2,3-di-O-benzyl-4,5-O-isopropylidene-L-arabinose di(ethylthio)acetal

下游产品

(E)-(5S,6S,7S)-5,6-Bis-benzyloxy-7,8-dihydroxy-oct-2-enoic acid methyl ester (2S,3R,4S,6S)-2-((benzoyloxy)methyl)-6-(2-methoxy-2-oxoethyl)tetrahydro-2H-pyran-3,4-diyl dibenzoate [2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]methanol (1R,6R,8S,9R)-8,9-Bis-benzyloxy-3,10-dioxa-bicyclo[4.3.1]decan-4-one