合成路线
(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate
CAS号：762252-31-3
英文名：(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate
分子式：C31H33N3O9S
分子量：623.673
上游原料
dimethyl 2-((1S,4R)-4-hydroxy-2-((tert-butyldimethylsilyloxy)methyl)cyclohex-2-enyl)-2-(3-(2-(tert-butyldimethylsilyloxy)ethyl)-1H-indol-2-yl)malonate
(1S,6S)-6-bromo-2-(hydroxymethyl)cyclohex-2-enol
dimethyl 2-(2-((Z)-3-(tert-butyldimethylsilyloxy)prop-1-enyl)phenylthiocarbamoyl)malonate
(5S,6S)-methyl 6-acetoxy-5-bromocyclohex-1-enecarboxylate
(Z)-(2-isothiocyanatocinnamyloxy)(tert-butyl)dimethylsilane
2-(cis-3-hydroxyprop-1-enyl)phenyl isothiocyanate
(((1S,6R)-7-oxa-bicyclo[4.1.0]hept-2-en-2-yl)methoxy)(tert-butyl)dimethylsilane
dimethyl 2-(3-(2-(tert-butyldimethylsilyloxy)ethyl)1H-indol-2-yl)malonate
下游产品
(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate
(-)-methyl (2S,3aS,5R,11bR)-3-benzyl-2,3,3a,4,5,7-hexahydro-3,5-ethano-12-(E)-<(methoxycarbonyl)methylene>-1H-pyrrolo<2,3-d>carbazole-6-carboxylates
(-)-methyl (2S,3aS,5R,11bR)-3-benzyl-2,3,3a,4,5,7-hexahydro-3,5-ethano-12-(E)-<(hydroxymethyl)methylene>-1H-pyrrolo<2,3-d>carbazole-6-carboxylates
(10R,11R)-9-[1-Methoxycarbonyl-meth-(E)-ylidene]-7-(2-nitro-benzenesulfonyl)-10-(2-oxo-ethyl)-6,7,8,9,10,11-hexahydro-5H-7,12-diaza-cyclonona[a]indene-11,12-dicarboxylic acid 12-tert-butyl ester 11-methyl ester
