(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

CAS号：762252-32-4

英文名：(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

分子式：C31H33N3O10S

分子量：639.673

合成路线

224315-42-8

2-(cis-3-hydroxyprop-1-enyl)phenyl isothiocyanate

762252-32-4

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

762252-36-8

(Z)-(2-isothiocyanatocinnamyloxy)(tert-butyl)dimethylsilane

762252-32-4

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

762252-37-9

dimethyl 2-(2-((Z)-3-(tert-butyldimethylsilyloxy)prop-1-enyl)phenylthiocarbamoyl)malonate

762252-32-4

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

762252-23-3

dimethyl 2-(3-(2-(tert-butyldimethylsilyloxy)ethyl)1H-indol-2-yl)malonate

762252-32-4

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

762252-31-3

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

762252-32-4

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

762252-28-8

dimethyl 2-((1S,4R)-4-hydroxy-2-((tert-butyldimethylsilyloxy)methyl)cyclohex-2-enyl)-2-(3-(2-(tert-butyldimethylsilyloxy)ethyl)-1H-indol-2-yl)malonate

762252-32-4

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-2-hydroxy-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate

上游原料

(14R,14aR)-13-tert-butyl-14-methyl-1,2,3,5,6,7,8,14,14a-nonahydro-3-oxo-6-(2-nitrobenzenesulfonyl)benzo[7,8]azonino[5,4-b]indole-13,14(1H)-dicarboxylate dimethyl 2-((1S,4R)-4-hydroxy-2-((tert-butyldimethylsilyloxy)methyl)cyclohex-2-enyl)-2-(3-(2-(tert-butyldimethylsilyloxy)ethyl)-1H-indol-2-yl)malonate dimethyl 2-(2-((Z)-3-(tert-butyldimethylsilyloxy)prop-1-enyl)phenylthiocarbamoyl)malonate (Z)-(2-isothiocyanatocinnamyloxy)(tert-butyl)dimethylsilane 2-(cis-3-hydroxyprop-1-enyl)phenyl isothiocyanate dimethyl 2-(3-(2-(tert-butyldimethylsilyloxy)ethyl)1H-indol-2-yl)malonate

下游产品

(-)-methyl (2S,3aS,5R,11bR)-3-benzyl-2,3,3a,4,5,7-hexahydro-3,5-ethano-12-(E)-<(methoxycarbonyl)methylene>-1H-pyrrolo<2,3-d>carbazole-6-carboxylates (-)-methyl (2S,3aS,5R,11bR)-3-benzyl-2,3,3a,4,5,7-hexahydro-3,5-ethano-12-(E)-<(hydroxymethyl)methylene>-1H-pyrrolo<2,3-d>carbazole-6-carboxylates