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(3aR,5S,5aS,8S,8aS,9aR)-8-羟基-8a-(羟基甲基)-5-甲基-1-亚甲基-4,5,5a,6,7,8,9,9a-八氢-3aH-薁并[7,6-D]呋喃-2-酮

(3aR,5S,5aS,8S,8aS,9aR)-8-羟基-8a-(羟基甲基)-5-甲基-1-亚甲基-4,5,5a,6,7,8,9,9a-八氢-3aH-薁并[7,6-D]呋喃-2-酮

CAS号：76467-15-7

英文名：(3aR,5S,5aS,8S,8aS,9aR)-8-hydroxy-8a-(hydroxymethyl)-5-methyl-1-methylidene-4,5,5a,6,7,8,9,9a-octahydro-3aH-azuleno[6,5-b]furan-2-one

分子式

C15H22O4

熔点

密度

1.23g/cm3

分子量

266.333

沸点

465.5ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

(3aR,5S,5aS,8S,8aS,9aR)-8-羟基-8a-(羟基甲基)-5-甲基-1-亚甲基-4,5,5a,6,7,8,9,9a-八氢-3aH-薁并[7,6-D]呋喃-2-酮

英文名称

(3aR,5S,5aS,8S,8aS,9aR)-8-hydroxy-8a-(hydroxymethyl)-5-methyl-1-methylidene-4,5,5a,6,7,8,9,9a-octahydro-3aH-azuleno[6,5-b]furan-2-one

中文别名

英文别名

Rudmollin

CAS号

76467-15-7

分子式

C15H22O4

分子量

266.333

精确质量

266.152

PSA

66.76

LOGP

1.2637

物化性质

密度

1.23g/cm3

沸点

465.5ºC at 760 mmHg

闪点

174.5ºC

折射率

1.557

合成路线

顺-4-己烯-1-醇

顺-4-己烯-1-醇

(3aR,5S,5aS,8S,8aS,9aR)-8-羟基-8a-(羟基甲基)-5-甲基-1-亚甲基-4,5,5a,6,7,8,9,9a-八氢-3aH-薁并[7,6-D]呋喃-2-酮

(3aR,5S,5aS,8S,8aS,9aR)-8-羟基-8a-(羟基甲基)-5-甲基-1-亚甲基-4,5,5a,6,7,8,9,9a-八氢-3aH-薁并[7,6-D]呋喃-2-酮

上游原料

共找到22个上游原料 >

(Z)-己-4-烯醛

(Z)-己-4-烯醛

(3S,3aR,5S,8R,8aR)-3a-Benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-8-methyl-1,2,3,3a,4,5,8,8a-octahydro-azulene

(3S,3aR,5S,8R,8aR)-3a-Benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-8-methyl-1,2,3,3a,4,5,8,8a-octahydro-azulene

(3S,3aR,5R,7R,8S,8aR,9S)-5-allyl-3-((tert-butyldimethylsilyl)oxy)-8-methyl-6-oxooctahydro-1H-3a,7-methanoazulen-9-yl benzoate

(3S,3aR,5R,7R,8S,8aR,9S)-5-allyl-3-((tert-butyldimethylsilyl)oxy)-8-methyl-6-oxooctahydro-1H-3a,7-methanoazulen-9-yl benzoate

(3R,3aS,7S,8R,8aS,9R)-3-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-8-methyl-octahydro-3a,7-methano-azulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-8-methyl-octahydro-3a,7-methano-azulen-6-one

己-4-炔-1-醇

己-4-炔-1-醇

((3S,3aR,5S,8R,8aR)-3-((tert-butyldimethylsilyl)oxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-8-methyl-1,2,3,3a,4,5,8,8a-octahydroazulen-3a-yl)methanol

((3S,3aR,5S,8R,8aR)-3-((tert-butyldimethylsilyl)oxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-8-methyl-1,2,3,3a,4,5,8,8a-octahydroazulen-3a-yl)methanol

上游原料

(Z)-己-4-烯醛 (3S,3aR,5S,8R,8aR)-3a-Benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-8-methyl-1,2,3,3a,4,5,8,8a-octahydro-azulene (3S,3aR,5R,7R,8S,8aR,9S)-5-allyl-3-((tert-butyldimethylsilyl)oxy)-8-methyl-6-oxooctahydro-1H-3a,7-methanoazulen-9-yl benzoate (3R,3aS,7S,8R,8aS,9R)-3-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-8-methyl-octahydro-3a,7-methano-azulen-6-one 己-4-炔-1-醇 ((3S,3aR,5S,8R,8aR)-3-((tert-butyldimethylsilyl)oxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-8-methyl-1,2,3,3a,4,5,8,8a-octahydroazulen-3a-yl)methanol 顺-4-己烯-1-醇 tert-Butyl-((2aR,3S,3aR,6S,6aR,6bS,6cR)-6c-methoxy-3-methyl-2a,3,3a,4,5,6,6b,6c-octahydro-cyclopenta[a]cyclopropa[gh]pentalen-6-yloxy)-dimethyl-silane (3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one ((3aS,5R,8S,8aS)-3a-Benzyloxymethyl-8-methyl-3-oxo-1,2,3,3a,4,5,8,8a-octahydro-azulen-5-yl)-acetic acid 三(二甲氨基)甲烷 (3aR,4aS,5S,7aS,8S,9aR)-4a-Benzyloxymethyl-5-hydroxy-8-methyl-decahydro-azuleno[6,5-b]furan-2-one (Z)-1-(2-methoxyphenyl)hex-4-en-1-ol (3S,3aR,5R,6R,7S,8S,8aR,9S)-5-allyl-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-8-methyloctahydro-1H-3a,7-methanoazulen-9-yl benzoate (3R,3aS,6S,7R,8R,8aS,9R)-3-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methano-azulene-6,9-diol (3aR,4aS,7aS,8S,9aR)-4a-((benzyloxy)methyl)-8-methyldecahydroazuleno[6,5-b]furan-2,5-dione (3S,3aR,7R,8S,8aR,9S)-3-((tert-butyldimethylsilyl)oxy)-8-methyl-6-oxooctahydro-1H-3a,7-methanoazulen-9-yl benzoate (3S,3aR,5S,6S,7S,8S,8aR,9S)-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-5-(2-hydroxyethyl)-8-methyloctahydro-1H-3a,7-methanoazulen-9-yl benzoate (Z)-tert-butyl((1-(2-methoxyphenyl)hex-4-en-1-yl)oxy)dimethylsilane (3R,3aR,6S,7R,8R,8aS)-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-8-methyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulen-9-one (3S,3aR,5S,6S,7S,8S,8aR,9S)-3-((tert-butyldimethylsilyl)oxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-6-hydroxy-8-methyloctahydro-1H-3a,7-methanoazulen-9-yl benzoate (3aR,4aS,5S,7aS,8S,9aR)-5-Hydroxy-4a-hydroxymethyl-8-methyl-decahydro-azuleno[6,5-b]furan-2-one