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(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

CAS号：765942-00-5

英文名：(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

分子式：C23H38O5Si

分子量：422.63

合成路线

(2S)-1-benzyloxy-2-tert-butyldimethylsilyloxypent-4-ene

(2S)-1-benzyloxy-2-tert-butyldimethylsilyloxypent-4-ene

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(1S,3S)-1-((1R)-1-methyl-2-propenyl)-4-benzyloxy-3-tert-butyldimethylsilyloxybutyl prop-2-enoate

(1S,3S)-1-((1R)-1-methyl-2-propenyl)-4-benzyloxy-3-tert-butyldimethylsilyloxybutyl prop-2-enoate

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-5-methyldihydropyran-2-one

(5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-5-methyldihydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(3S,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-3,4-dihydroxy-5-methyltetrahydropyran-2-one

(3S,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-3,4-dihydroxy-5-methyltetrahydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

(3R,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one

上游原料

(2S)-1-benzyloxy-2-tert-butyldimethylsilyloxypent-4-ene (5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-5-methyldihydropyran-2-one (3S,4S,5R,6S)-6-((2S)-3-benzyloxy-2-tert-butyldimethylsilyloxypropyl)-3,4-dihydroxy-5-methyltetrahydropyran-2-one (1S,3S)-1-((1R)-1-methyl-2-propenyl)-4-benzyloxy-3-tert-butyldimethylsilyloxybutyl prop-2-enoate

下游产品

(2S)-2-tert-butyldimethylsilyloxy-3-[(2S,3S,4S,5R)-4-tert-butyldimethylsilyloxy-3,5-dimethyl-6-oxotetrahydropyran-2-yl]propanal (3R,4S,5R,6S)-6-((2S)-2-tert-butyldimethylsilyloxy-3-hydroxypropyl)-4-tert-butyldimethylsilyloxy-3,5-dimethyltetrahydropyran-2-one