百科

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

CAS号：768395-39-7

英文名：(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

分子式：C34H55NO8

分子量：605.802

合成路线

(E)-(2S,4S,6R,8S,15S)-15-(tert-Butyl-dimethyl-silanyloxy)-15-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-2,4,6,8-tetramethyl-9-oxo-pentadec-12-en-10-ynal

(E)-(2S,4S,6R,8S,15S)-15-(tert-Butyl-dimethyl-silanyloxy)-15-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-2,4,6,8-tetramethyl-9-oxo-pentadec-12-en-10-ynal

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

(E)-(1S,8S,10R,12S,14S)-1-(tert-Butyl-dimethyl-silanyloxy)-15-hydroxy-1-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-8,10,12,14-tetramethyl-pentadec-3-en-5-yn-7-one

(E)-(1S,8S,10R,12S,14S)-1-(tert-Butyl-dimethyl-silanyloxy)-15-hydroxy-1-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-8,10,12,14-tetramethyl-pentadec-3-en-5-yn-7-one

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

(E)-(3S,4S,6S,8R,10S,17S)-17-Hydroxy-17-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-3-methoxymethoxy-4,6,8,10-tetramethyl-11-oxo-heptadec-14-en-12-ynoic acid 4-methoxy-benzyl ester

(E)-(3S,4S,6S,8R,10S,17S)-17-Hydroxy-17-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-3-methoxymethoxy-4,6,8,10-tetramethyl-11-oxo-heptadec-14-en-12-ynoic acid 4-methoxy-benzyl ester

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

(4E,6Z)-(2S,9S,11R,13S,15S,16S)-2-[(1R,2R)-2-(2-Methoxy-ethoxymethoxymethyl)-cyclopentyl]-16-methoxymethoxy-9,11,13,15-tetramethyl-8,18-dioxo-oxacyclooctadeca-4,6-diene-7-carbonitrile

上游原料

(E)-(2S,4S,6R,8S,15S)-15-(tert-Butyl-dimethyl-silanyloxy)-15-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-2,4,6,8-tetramethyl-9-oxo-pentadec-12-en-10-ynal (E)-(1S,8S,10R,12S,14S)-1-(tert-Butyl-dimethyl-silanyloxy)-15-hydroxy-1-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-8,10,12,14-tetramethyl-pentadec-3-en-5-yn-7-one (E)-(3S,4S,6S,8R,10S,17S)-17-Hydroxy-17-[(1R,2R)-2-(2-methoxy-ethoxymethoxymethyl)-cyclopentyl]-3-methoxymethoxy-4,6,8,10-tetramethyl-11-oxo-heptadec-14-en-12-ynoic acid 4-methoxy-benzyl ester

下游产品

抗螺旋体链丝菌素