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Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

CAS号：769126-86-5

英文名：Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

分子式：C34H50O8SSi

分子量：646.906

合成路线

methyl 4,6-O-benzylidene-3-deoxy-3-C-(3-hydroxypropyl)-α-D-altopyranoside

methyl 4,6-O-benzylidene-3-deoxy-3-C-(3-hydroxypropyl)-α-D-altopyranoside

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

methyl 4,6-O-benzylidene-2-(tert-butyldimethylsilyloxy)-3-deoxy-3-[(3-pivaloyloxy)propyl]-α-D-altropyranoside

methyl 4,6-O-benzylidene-2-(tert-butyldimethylsilyloxy)-3-deoxy-3-[(3-pivaloyloxy)propyl]-α-D-altropyranoside

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

Benzoic acid (1R,2R)-2-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonyloxy)-ethyl]-5-(2,2-dimethyl-propionyloxy)-1-vinyl-pentyl ester

上游原料

methyl 4,6-O-benzylidene-2-(tert-butyldimethylsilyloxy)-3-deoxy-3-[(3-pivaloyloxy)propyl]-α-D-altropyranoside methyl 4,6-O-benzylidene-3-deoxy-3-C-(3-hydroxypropyl)-α-D-altopyranoside methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

下游产品

(3R,4R,5S)-3,5-bis[(tert-butyldimethylsilyl)oxy]-4-[3-{(tert-butyldimethylsilyl)oxy}propyl]oct-1-en-7-yne