百科

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

CAS号：77234-49-2

英文名：[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

分子式：C42H63O9PSi

分子量：771.003

合成路线

77234-42-5

(E)-(4S,5S,6R)-8-Benzyloxy-4,6-dihydroxy-5-methoxy-oct-2-enoic acid methyl ester

77234-49-2

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

77234-56-1

(E)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-acrylic acid methyl ester

77234-49-2

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

78306-80-6

(4R,5S)-5-((1S,2R)-4-Benzyloxy-2-hydroxy-1-methoxy-butyl)-4-(2-methyl-allyl)-dihydro-furan-2-one

77234-49-2

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

77234-46-9

{(R)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-5-methyl-hex-5-enyloxy}-tert-butyl-diphenyl-silane

77234-49-2

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

78249-07-7

6-O-Benzyl-5-deoxy-3-O-methyl-D-glucofuranose

77234-49-2

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

77234-45-8

(3R,4S,5S,6R)-1-Benzyloxy-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methoxy-8-methyl-non-8-ene-3,5-diol

77234-49-2

[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester

上游原料

(E)-(4S,5S,6R)-8-Benzyloxy-4,6-dihydroxy-5-methoxy-oct-2-enoic acid methyl ester (3R,4S,5S,6R)-1-Benzyloxy-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methoxy-8-methyl-non-8-ene-3,5-diol (4R,5S)-5-((1S,2R)-4-Benzyloxy-2-hydroxy-1-methoxy-butyl)-4-(2-methyl-allyl)-dihydro-furan-2-one {(R)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-5-methyl-hex-5-enyloxy}-tert-butyl-diphenyl-silane 6-O-Benzyl-5-deoxy-3-O-methyl-D-glucofuranose (E)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-acrylic acid methyl ester

下游产品

{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid