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{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
CAS号:77243-15-3
英文名:{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
分子式:C35H53O10PSi
分子量:692.849
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合成路线
77234-42-5
(E)-(4S,5S,6R)-8-Benzyloxy-4,6-dihydroxy-5-methoxy-oct-2-enoic acid methyl ester
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
77234-56-1
(E)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-acrylic acid methyl ester
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
77234-48-1
(R)-4-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-6-(tert-butyl-diphenyl-silanyloxy)-2-methyl-hexanal
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
78306-80-6
(4R,5S)-5-((1S,2R)-4-Benzyloxy-2-hydroxy-1-methoxy-butyl)-4-(2-methyl-allyl)-dihydro-furan-2-one
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
77241-77-1
{(3R,5R)-7-(tert-Butyl-diphenyl-silanyloxy)-5-[(4S,5S,6R)-6-(2-hydroxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-3-methyl-2-oxo-heptyl}-phosphonic acid dimethyl ester
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
62853-46-7
5-deoxy-3-O-methyl-1,2-O-(methylethylidene)-α-D-xylo-hexo-furanose
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
78249-07-7
6-O-Benzyl-5-deoxy-3-O-methyl-D-glucofuranose
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
77234-49-2
[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
77243-14-2
[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-heptyl]-phosphonic acid dimethyl ester
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
77234-44-7
(S)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-5-methyl-hex-5-enoic acid methyl ester
77243-15-3
{(4R,5S,6S)-6-[(1R,3R)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-(dimethoxy-phosphoryl)-3-methyl-4-oxo-pentyl]-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid
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上游原料
(R)-4-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-6-(tert-butyl-diphenyl-silanyloxy)-2-methyl-hexanal
(E)-(4S,5S,6R)-8-Benzyloxy-4,6-dihydroxy-5-methoxy-oct-2-enoic acid methyl ester
(3R,4S,5S,6R)-1-Benzyloxy-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methoxy-8-methyl-non-8-ene-3,5-diol
[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-heptyl]-phosphonic acid dimethyl ester
(S)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-5-methyl-hex-5-enoic acid methyl ester
{(3R,5R)-7-(tert-Butyl-diphenyl-silanyloxy)-5-[(4S,5S,6R)-6-(2-hydroxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-3-methyl-2-oxo-heptyl}-phosphonic acid dimethyl ester
{(R)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-5-methyl-hex-5-enyloxy}-tert-butyl-diphenyl-silane
(4R,5S)-5-((1S,2R)-4-Benzyloxy-2-hydroxy-1-methoxy-butyl)-4-(2-methyl-allyl)-dihydro-furan-2-one
[(R)-5-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-7-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-heptyl]-phosphonic acid dimethyl ester
6-O-Benzyl-5-deoxy-3-O-methyl-D-glucofuranose
(E)-3-[(4S,5S,6R)-6-(2-Benzyloxy-ethyl)-5-methoxy-2,2-dimethyl-[1,3]dioxan-4-yl]-acrylic acid methyl ester
5-deoxy-3-O-methyl-1,2-O-(methylethylidene)-α-D-xylo-hexo-furanose
(-)-5-Deoxy-6-O-benzyl-1,2-di-O-isopropylidene-3-O-methyl-D-glucofuranose
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