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(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester

(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester

CAS号：77449-58-2
英文名：(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
分子式：C34H68O6SSi
分子量：633.051
合成路线
(2S,3R)-2-methyl-3-hydroxypentanoic acid
77405-43-7
(2S,3R)-2-methyl-3-hydroxypentanoic acid
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
77449-58-2
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
78655-82-0
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
77449-58-2
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
(R)-2-[(4S,5R,6S)-6-((1S,3R)-1,3-Dimethyl-4-oxo-hexyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
77405-50-6
(R)-2-[(4S,5R,6S)-6-((1S,3R)-1,3-Dimethyl-4-oxo-hexyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
77449-58-2
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
(2S,3R)-2-methyl-3-<(triethylsilyl)oxy>pentanal
77405-44-8
(2S,3R)-2-methyl-3-<(triethylsilyl)oxy>pentanal
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
77449-58-2
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
(2R,4S)-4-[(4S,5R,6S)-6-((R)-1-tert-Butylsulfanylcarbonyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid
77405-49-3
(2R,4S)-4-[(4S,5R,6S)-6-((R)-1-tert-Butylsulfanylcarbonyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
77449-58-2
(R)-2-[(4S,5R,6S)-6-((1S,3R,5S,6R,7R,8R)-4,6-Dihydroxy-1,3,5,7-tetramethyl-8-triethylsilanyloxy-decyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
上游原料
(2S,3R)-2-methyl-3-<(triethylsilyl)oxy>pentanal (2R,4S)-4-[(4S,5R,6S)-6-((R)-1-tert-Butylsulfanylcarbonyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid (2S,3R)-2-methyl-3-hydroxypentanoic acid (R)-2-[(4S,5R,6S)-6-((1S,3R)-1,3-Dimethyl-4-oxo-hexyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-thiopropionic acid S-tert-butyl ester
下游产品
(9S)-6,12-Dideoxy-9-deoxo-9-hydroxy-3,5-O-(1-methylethylidene)erythronolide A ((9S)-Dihydro-6-deoxy-erythronolide B) 3,5-Acetonide (1S,2R,5R,6R,7S,8R,10R,12S,13S,17R)-5-Ethyl-7-hydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione
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