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[(1S,3S,4aR,7S,8S,8aR)-8-[2-[(2R,4R)-4-羟基-6-氧代四氢吡喃-2-基]乙基]-3,7-二甲基-1,2,3,4,4a,7,8,8a-八氢萘-1-基] (2S)-2-甲基丁酸酯

[(1S,3S,4aR,7S,8S,8aR)-8-[2-[(2R,4R)-4-羟基-6-氧代四氢吡喃-2-基]乙基]-3,7-二甲基-1,2,3,4,4a,7,8,8a-八氢萘-1-基] (2S)-2-甲基丁酸酯

CAS号:77517-29-4
英文名:(1S,3S,4aR,7S,8S,8aR)-8-{2-[(2R,4R)-4-Hydroxy-6-oxotetrahydro-2H- pyran-2-yl]ethyl}-3,7-dimethyl-1,2,3,4,4a,7,8,8a-octahydro-1-naph thalenyl (2S)-2-methylbutanoate
分子式:C24H38O5
分子量:406.556
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上游原料
(2S,4R,5S,6E,8E)-1-<(tert-butyldiphenylsilyl)oxy>-5-(methoxymethoxy)-4-methyl-2-<(trimethylsilyl)oxy>-6,8-decadiene (2Z,4S,6R,8E,10E)-7-(methoxymethoxy)-6-methyl-2,8,10-dodecatrien-1,4-olide (3R,5S)-dimethyl-<6-<(tert-butyldiphenylsilyl)oxy>-3-methyl-2-oxo-5-(trimethylsiloxy)hexyl>phosphonate (1R,2S,4aR,6S,8S,8aS)-1-(acetoxymethyl)-8-[(tert-butyldimethylsilyl)oxy]-2,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalene (3aRS,4SR,8SR,9aSR,9bRS)-2,3,3a,4,5,7,8,9,9a,9b-decahydro-4,8-dimethyl-3-oxonaphtho<1,8-bc>pyran p-toluenesulfonylhydrazone (2S,4R,5S,6E,8E)-1-[[(2',4',6'-triisopropylphenyl)-sulfonyl]oxy]-5-(methoxymethoxy)-4-methyl-6,8-decadien-2-ol 6(R)-(2-(1,2,3,4,6,7,8,8a(R)-Octahydro-2(R),6(R)-dimethyl-8(S)-((2(S)-methylbutyryl)oxy)-3(S),4(R)-dihydroxy-1(S)-naphthyl)ethyl)-3,4,5,6-tetrahydro-4(R)-((tert-butyldimethylsilyl)oxy)-2H-pyran-2-one O-((2aR,2a1S,3S,5aR,6S,7R,8aS)-3,7-dimethyl-2-oxo-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-6-yl) S-methyl carbonodithioate (1RS,2SR,6SR,8SR,8aRS)-1,2,3,5,6,7,8,8a-octahydro-8-(acetyloxy)-2,6-dimethyl-1-ethenylnaphthalene (1SR,2SR,4aSR,6SR,8SR,8aRS)-8-(acetyloxy)-2,6-dimethyl-1-formyl-4-oxodecahydronaphthalene (1R,2S,4aR,6S,8S,8aS)-2,6-dimethyl-1-(hydroxymethyl)-8-hydroxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene (1RS,2SR,4aSR,6SR,8SR,8aRS)-8-(acetyloxy)-2,6-dimethyl-1-ethenyl-4-oxodecahydronaphthalene (3aRS,4SR,8SR,9aSR,9bRS)-2,3,3a,4,5,7,8,9,9a,9b-decahydro-3-oxo-4,8-dimethylnaphtho<1,8-bc>pyran (1S,2S,4aR,6S,8S,8aS)-1-(nitroethyl)-2,6-dimethyl-8-hydroxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene (1S,3S,4aS,7S,8S,8aS)-8-(hydroxymethyl)-3,7-dimethyl-5-(2-tosylhydrazono)decahydronaphthalen-1-yl acetate (1R,2S,4aR,6S,8S,8aS)-1-(2-nitro-1-ethenyl)-2,6-dimethyl-8-[(tert-butyldimethylsilyl)oxy]-1,2,4a,5,6,7,8,8a-octahydronaphthalene 5-O-(tert-butyldiphenylsilyl)-2,3-dideoxy-2-C-methyl-D-threo-pentonic-γ-lactone (2α,4α,4aβ,5β,6β,8aα)-octahydro-5-(hydroxymethyl)-2,6-dimethylnaphthalen-4-ol (2S,4R,5S,6E,8E)-1-((tert-butyldiphenylsilyl)oxy)-4-methyl-2-((trimethylsilyl)oxy)-6,8-decadien-5-ol methyl (1S,2S,4aR,6S,8S,8aS,3'R,2''S)-3'-(tert-butyldimethylsiloxy)-7'-[1,2,4a,5,6,7,8,8a-octahydro-2,6-dimethyl-8-[(2''-methylbutyryl)oxy]-1-naphthalenyl]-5'-oxohept-6'-enoate (1S,2S,4aR,8aR)-2-Methyl-8-oxo-1,2,4a,5,8,8a-hexahydro-naphthalene-1-carboxylic acid methyl ester (1R,2S,4aR,6S,8S,8aS)-8-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde (1S,2S,4aR,6S,8S,8aS,5'R,2''S)-methyl-1,2,4a,5,6,7,8,8a-octahydro-2,6-dimethyl-5'-hydroxy-8-<(2-methyl-1-oxobutyl)oxy>-3'-oxo-1-naphthaleneheptanoate (1S,2S,4aR,6S,8S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-2,6-dimethyl-1-formyl-8-[(S)-(2-methylbutyryl)oxy]naphthalene (1S,2S,4aR,6S,8S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-2,6-dimethyl-8-((S)-(2-methylbutyryl)oxy)-1-(((R)-(O-methylmandelyl)oxy)methyl)naphthalene (3aS,4S,7R,7aR)-4-methyl-7-(3-(phenylsulfinyl)propyl)-3a,4,7,7a-tetrahydroisobenzofuran-1,3-dione (1RS,2SR,6SR,8SR,8aRS)-1,2,3,5,6,7,8,8a-octahydro-2,6-dimethyl-8-hydroxy-1-ethenylnaphthalene (1R,2S,4aR,5S,6R,8S,8aS)-1-carboxy-2,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalene-5,8-diol 1,8-lactone (1S,2S,4aR,6S,8S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-2,6-dimethyl-8-hydroxy-1-([(R)-(O-methylmandelyl)oxy]methyl)naphthalene O-benzyldihydromevinolin (1R,2S,4aR,6S,8S,8aS)-8-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-1-(hydroxymethyl)-1,2,4a,5,6,7,8,8a-octahydronaphthalene (1R,2S,4aR,6S,8S,8aS)-1-carboxy-2,6-dimethoxy-8-hydroxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene 1,8 lactone (2S,4R,5S,6E,8E)-5-(methoxymethoxy)-4-methyl-6,8-decadien-1,2-diol (1RS,2SR,4RS,4aSR,6RS,8SR,8aSR)-8-(acetyloxy)-2,6-dimethyl-4,4a-epoxy-1-ethenyldecahydronaphthalene (1R,2S,4aR,5S,6R,8S,8aS)-1-carboxy-5-(methoxymethoxy)-2,6-dimethyl-8-hydroxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene 1,8-lactone (1RS,2SR,6SR,8SR,8aRS)-1,2,3,5,6,7,8,8a-octahydro-2,6-dimethyl-1-ethynyl-8-hydroxynaphthalene (1SR,2SR,4aSR,6SR,8SR,8aRS)-8-(acetyloxy)-2,6-dimethyl-1-hydroxymethyl-4-oxodecahydronaphthalene (2S,4R,6E,8E)-1-<(tert-butyldiphenylsilyl)oxy>-4-methyl-2-<(trimethylsilyl)oxy>-6,8-decadien-5-one (1S,2S,4aR,6S,8S,8aS,3'R,5'R,2''S)-methyl-1,2,4a,5,6,7,8,8a-octahydro-3',5'-dihydroxy-2,6-dimethyl-8-((2-methyl-1-oxobutyl)oxy)-1-naphthaleneheptanoate (1RS,2SR,4aSR,6SR,8SR,8aRS)-8-(acetyloxy)-2,6-dimethyl-1-formyl-4-oxodecahydronaphthalene (1S,2S,4aR,6S,8S,8aS)-1-(2-nitroethyl)-2,6-dimethyl-8-[(tert-butyldimethylsilyl)oxy]-1,2,4a,5,6,7,8,8a-octahydronaphthalene methyl (1R,2R,4aS,6R,8aR)-2,6-dimethyl-8-oxo-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxylate (1S,2S,4aR,6S,8S,8aS)-1-[2-[3(R)-[4(R)-[[tert-butyldimethylsilyl]oxy]-1-oxo-3-cyclopentyl]]ethyl]-2,6-dimethyl-8-[[(S)-2-methyl-1-oxobutyl]oxy]-1,2,4a,5,6,7,8,8a-octahydronaphthalene (1S,2S,4aR,6S,8S,8aS)-1-(2-nitroethyl)-2,6-dimethyl-8-<<(S)-2-methyl-1-oxobutyl>oxy>-1,2,4a,5,6,7,8,8a-octahydronaphthalene