百科

(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

CAS号：778640-35-0

英文名：(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

分子式：C31H51NO8Si

分子量：593.824

合成路线

(1S,2R,3R,6R)-2-[(4S)-3-(tert-butoxycarbonyl-2,2-dimethyloxazolidin-4-yl)methyl]-1,2-O-isopropylidene-6-(p-methoxybenzyloxy)-4-cyclohexene-1,2,3-triol

(1S,2R,3R,6R)-2-[(4S)-3-(tert-butoxycarbonyl-2,2-dimethyloxazolidin-4-yl)methyl]-1,2-O-isopropylidene-6-(p-methoxybenzyloxy)-4-cyclohexene-1,2,3-triol

(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

(1S,2S,3R,6R)-1-{[(4S)-3-tert-butoxycarbonyl-2,2-dimethyloxazolidin-4-yl]methyl}-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

(1S,2S,3R,6R)-1-{[(4S)-3-tert-butoxycarbonyl-2,2-dimethyloxazolidin-4-yl]methyl}-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

(1S,2S,3R,6R)-1-[(2S)-2-(tert-butoxycarbonylamino)-3-hydroxypropyl]-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

上游原料

(1S,2R,3R,6R)-2-[(4S)-3-(tert-butoxycarbonyl-2,2-dimethyloxazolidin-4-yl)methyl]-1,2-O-isopropylidene-6-(p-methoxybenzyloxy)-4-cyclohexene-1,2,3-triol (1S,2S,3R,6R)-1-{[(4S)-3-tert-butoxycarbonyl-2,2-dimethyloxazolidin-4-yl]methyl}-6-(tert-butyldimethylsiloxy)-1,2-O-isopropylidene-3-(4-methoxybenzyloxy)cyclohex-4-ene-1,2-diol

下游产品

(2E,4E,6E,8R,10S,12E,14R)-N-{(1S)-2-[(3aS,4R,7R,7aS)-4-(tert-butyldimethylsiloxy)-7-hydroxy-2,2-dimethyl-7,7a-dihydro-1,3-benzodioxol-3a(4H)-yl]-1-(hydroxymethyl)ethyl}-8,10,12,14-tetramethylhexadeca-2,4,6,12-tetraenamide