百科

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

CAS号：780772-39-6

英文名：(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

分子式：C27H31F15O3

分子量：688.509

合成路线

(2S,3S)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-butyraldehyde

(2S,3S)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-butyraldehyde

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(4S,5R)-4,5-dimethyl-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecyloxy)phenyl]-[1,3]dioxane

(4S,5R)-4,5-dimethyl-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecyloxy)phenyl]-[1,3]dioxane

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

ethyl (2S,3S)-3-hydroxy-2-methylbutanoate

ethyl (2S,3S)-3-hydroxy-2-methylbutanoate

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

(E)-(2S,6R,7S)-2,6-Dimethyl-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-oct-4-en-1-ol

上游原料

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol (4S,5R)-4,5-dimethyl-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecyloxy)phenyl]-[1,3]dioxane ethyl (2S,3S)-3-hydroxy-2-methylbutanoate (2S,3S)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-decyloxy)-benzyloxy]-butyraldehyde (3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

下游产品

(2S,3R,7R,11R)-3,7,11-trimethyl-2-tridecanol (2S,3R,7R,11S)-3,7,11-trimethyl-2-tridecanol