百科

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

CAS号：780772-40-9

英文名：(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

分子式：C28H31F17O3

分子量：738.517

合成路线

ethyl (2S,3S)-3-hydroxy-2-methylbutanoate

ethyl (2S,3S)-3-hydroxy-2-methylbutanoate

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

4-nitrobenzoic acid (1R,2S)-2-ethoxycarbonyl-1-methylpropyl ester

4-nitrobenzoic acid (1R,2S)-2-ethoxycarbonyl-1-methylpropyl ester

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(4R,5R)-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyloxy)phenyl]-4,5-dimethyl-[1,3]dioxane

(4R,5R)-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyloxy)phenyl]-4,5-dimethyl-[1,3]dioxane

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

(E)-(2S,6R,7R)-7-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6-dimethyl-oct-4-en-1-ol

上游原料

4-nitrobenzoic acid (1R,2S)-2-ethoxycarbonyl-1-methylpropyl ester (3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol ethyl (2S,3S)-3-hydroxy-2-methylbutanoate (3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole (4R,5R)-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyloxy)phenyl]-4,5-dimethyl-[1,3]dioxane

下游产品

(2R,3R,7R,11S)-3,7,11-trimethyl-2-tridecanol