百科

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

CAS号：780772-87-4

英文名：(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

分子式：C33H37F17O3

分子量：804.618

合成路线

(3R)-4-(tert-butyldimethylsilanyloxy)-3-methylbutyraldehyde

(3R)-4-(tert-butyldimethylsilanyloxy)-3-methylbutyraldehyde

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

ethyl (2S,3S)-3-hydroxy-2-methylbutanoate

ethyl (2S,3S)-3-hydroxy-2-methylbutanoate

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

4-nitrobenzoic acid (1R,2S)-2-ethoxycarbonyl-1-methylpropyl ester

4-nitrobenzoic acid (1R,2S)-2-ethoxycarbonyl-1-methylpropyl ester

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4R,5R)-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyloxy)phenyl]-4,5-dimethyl-[1,3]dioxane

(4R,5R)-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyloxy)phenyl]-4,5-dimethyl-[1,3]dioxane

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(3R)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(3R)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

(4E,8E)-(2R,6S,10R,11R)-11-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoro-undecyloxy)-benzyloxy]-2,6,10-trimethyl-dodeca-4,8-dienal

上游原料

(3R)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole 4-nitrobenzoic acid (1R,2S)-2-ethoxycarbonyl-1-methylpropyl ester (3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol (3R)-4-(tert-butyldimethylsilanyloxy)-3-methylbutyraldehyde ethyl (2S,3S)-3-hydroxy-2-methylbutanoate (3S)-5-[4-(tert-butyldimethylsilanyloxy)-3-methylbutane-1-sulfonyl]-1-phenyl-1H-tetrazole (4R,5R)-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyloxy)phenyl]-4,5-dimethyl-[1,3]dioxane

下游产品

(2R,3R,7R,11S)-3,7,11-trimethyl-2-tridecanol