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冈田(软海绵)酸

冈田(软海绵)酸

CAS号:78111-17-8
英文名:okadaic acid
分子式:C44H68O13
分子量:805.003
上游原料
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上游原料
((2S,5R,6S,8S)-5-(benzyloxy)-8-((R)-1-((4-methoxybenzyl)oxy)propan-2-yl)-10-methyl-1,7-dioxaspiro[5.5]undec-10-en-2-yl)methanol (1R,3S)-1-{(2S,4R,4aR,6R,8aR)-4-Benzyloxy-6-methoxy-6-[3-(4-methoxy-benzyloxy)-propyl]-3-methylene-octahydro-pyrano[3,2-b]pyran-2-yl}-3-((2S,3R,6S)-3-methyl-1,7-dioxa-spiro[5.5]undec-2-yl)-butan-1-ol (3R,6S)-3-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-pyran-2-one (Z)-(2S,5R,10S,11R)-5-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-12-(4-methoxy-benzyloxy)-8,11-dimethyl-2,10-bis-trimethylsilanyloxy-dodec-7-en-6-one (2S,5R)-5-({(2S,5R,6S,8S)-5-Benzyloxy-8-[(R)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-10-methyl-1,7-dioxa-spiro[5.5]undec-10-en-2-yl}-hydroxy-methyl)-2-tert-butyl-5-methyl-[1,3]dioxolan-4-one (4S,9R,12S)-9-(benzyloxy)-12-hydroxy-4-((R)-1-((4-methoxybenzyl)oxy)propan-2-yl)-2,2,16,16-tetramethyl-15,15-diphenyl-3,14-dioxa-2,15-disilaheptadec-6-yn-8-one {(2S,4R,4aR,6R,8aR)-4-Benzyloxy-6-methoxy-6-[3-(4-methoxy-benzyloxy)-propyl]-3-methylene-octahydro-pyrano[3,2-b]pyran-2-ylmethoxy}-tert-butyl-dimethyl-silane (2R,3R)-3,4-diethylmethylenedioxy-2-methyl-butan-1-ol (2S,5R)-5-(((2S,5R,6R,8S)-5-(benzyloxy)-8-((R)-1-((4-methoxybenzyl)oxy)propan-2-yl)-10-methyl-1,7-dioxaspiro[5.5]undec-10-en-2-yl)methyl)-2-(tert-butyl)-5-methyl-1,3-dioxolan-4-one (S)-2-((2S,6R,8S,11R)-11-(benzyloxy)-8-(((2S,4R)-2-(tert-butyl)-4-methyl-5-oxo-1,3-dioxolan-4-yl)methyl)-4-methyl-1,7-dioxaspiro[5.5]undec-4-en-2-yl)propanal (R)-2,2-Diethyl-4-[(R)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-[1,3]dioxolane (2R,4a'R,5R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-carbaldehyde (((2R,4a'R,5R,6'S,8'R,8a'R)-8'-(benzyloxy)-6'-((1S,3S)-1-(benzyloxy)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-5-yl)methoxy)(tert-butyl)diphenylsilane dimethyl (4-((2S,4aR,6S,8R,8aR)-8-(benzyloxy)-6-((1S,3S)-1-(benzyloxy)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-2-methoxy-7-methyleneoctahydropyrano[3,2-b]pyran-2-yl)-2-oxobutyl)phosphonate (2R,4aR,6S,8R,8aR)-8-Benzyloxy-6-[(1S,3S)-1-benzyloxy-3-((2S,3R,6S)-3-methyl-1,7-dioxa-spiro[5.5]undec-2-yl)-butyl]-2-methoxy-2-[3-(4-methoxy-benzyloxy)-propyl]-7-methylene-octahydro-pyrano[3,2-b]pyran (1S,3S)-1-((2R,4a'R,5R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-ol (6R)-1-((4aR,6R,7R,8S,8aR)-7-(benzyloxy)-8-(methoxymethoxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-yl)-7-((tert-butyldiphenylsilyl)oxy)-6-(1-ethoxyethoxy)heptan-3-one 3-((2S,4aR,6S,8R,8aR)-8-(benzyloxy)-6-((1S,3S)-1-(benzyloxy)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-2-methoxy-7-methyleneoctahydropyrano[3,2-b]pyran-2-yl)propanal (2S,5R)-5-((S)-((2S,5R,6S,8S)-5-(benzyloxy)-8-((R)-1-((4-methoxybenzyl)oxy)propan-2-yl)-10-methyl-1,7-dioxaspiro[5.5]undec-10-en-2-yl)(hydroxy)methyl)-2-(tert-butyl)-5-methyl-1,3-dioxolan-4-one (1S,3S)-1-((2S,4R,4aR,6R,8aR)-4-(benzyloxy)-6-methoxy-6-(3-((4-methoxybenzyl)oxy)propyl)-3-methyleneoctahydropyrano[3,2-b]pyran-2-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-ol (2R,4a'R,5R,6'S,8'R,8a'R)-8'-(benzyloxy)-6'-((1S,3S)-1-(benzyloxy)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-5-carbaldehyde (2S,5R,6S,8S)-5-Benzyloxy-8-[(R)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-10-methyl-1,7-dioxa-spiro[5.5]undec-10-ene-2-carbaldehyde (2R,3R,4R,4aR,6R,8aR)-4-(benzyloxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-6-methoxy-6-(3-((4-methoxybenzyl)oxy)propyl)octahydropyrano[3,2-b]pyran-3-ol (S)-1-{(2S,4R,4aR,6R,8aR)-4-Benzyloxy-6-methoxy-6-[3-(4-methoxy-benzyloxy)-propyl]-3-methylene-octahydro-pyrano[3,2-b]pyran-2-yl}-3-((2S,3R,6S)-3-methyl-1,7-dioxa-spiro[5.5]undec-2-yl)-butan-1-one (((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)trimethylsilane (2S,5R)-5-[(2S,5R,6R,8S)-5-Benzyloxy-8-((R)-2-hydroxy-1-methyl-ethyl)-10-methyl-1,7-dioxa-spiro[5.5]undec-10-en-2-ylmethyl]-2-tert-butyl-5-methyl-[1,3]dioxolan-4-one (4S,9R,12S)-9-(benzyloxy)-4-((R)-1-((4-methoxybenzyl)oxy)propan-2-yl)-2,2,16,16-tetramethyl-15,15-diphenyl-12-((trimethylsilyl)oxy)-3,14-dioxa-2,15-disilaheptadec-6-yn-8-one (2R,3S)-1-[(4-methoxyphenyl)methoxy]-2-methylhex-5-yn-3-ol {(2S,5R,6S,8S)-5-Benzyloxy-8-[(R)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-10-methyl-1,7-dioxa-spiro[5.5]undec-10-en-2-ylmethoxy}-tert-butyl-diphenyl-silane tribenzyl okadaic acid (R)-1-((2R,3R,4R,5R,6R)-3-(benzyloxy)-5-hydroxy-6-(hydroxymethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)-7-((tert-butyldiphenylsilyl)oxy)-6-hydroxyheptan-3-one ((2S,4R,4aR,6R,8aR)-4-(benzyloxy)-6-methoxy-6-(3-((4-methoxybenzyl)oxy)propyl)-3-methyleneoctahydropyrano[3,2-b]pyran-2-yl)methanol 1,2-O-(S)-pivalidene-7,24,27-tri-O-benzylokadaic acid (2R,3R,4R,4aR,6R,8aR)-4-(benzyloxy)-2-(hydroxymethyl)-6-methoxy-6-(3-((4-methoxybenzyl)oxy)propyl)octahydropyrano[3,2-b]pyran-3-ol (((2S,5R,6R)-5-(benzyloxy)-6-(phenylthio)tetrahydro-2H-pyran-2-yl)methoxy)(tert-butyl)diphenylsilane (2R,4a'R,5R,6'S,8'R,8a'S)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol 3-((4aR,6R,7R,8S,8aR)-7-Benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-propionaldehyde (2R,3R)-4-((4-methoxybenzyl)oxy)-3-methylbutane-1,2-diol (2R,3S)-1-(4-Methoxy-benzyloxy)-2-methyl-6-trimethylsilanyl-hex-5-yn-3-ol (S)-1-((2R,4a'R,5R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-one 3-((2R,4aR,6S,8R,8aR)-8-(benzyloxy)-6-((1S,3S)-1-(benzyloxy)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-2-methoxy-7-methyleneoctahydropyrano[3,2-b]pyran-2-yl)propan-1-ol