百科

Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

CAS号：78686-52-9

英文名：Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

分子式：C23H26O7S

分子量：446.513

合成路线

(3S,3aS,5R,6R,7R,7aR)-6-Benzyloxy-5-hydroxymethyl-7-iodo-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

(3S,3aS,5R,6R,7R,7aR)-6-Benzyloxy-5-hydroxymethyl-7-iodo-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

1,5-anhydro-2-deoxy-3-O-propanoyl-4-O-benzyl-6-O-(tert-butyldimethylsilyl)-D-gluco-hex-1-enitol

1,5-anhydro-2-deoxy-3-O-propanoyl-4-O-benzyl-6-O-(tert-butyldimethylsilyl)-D-gluco-hex-1-enitol

Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

上游原料

(3S,3aS,5R,6R,7R,7aR)-6-Benzyloxy-5-hydroxymethyl-7-iodo-3-methyl-hexahydro-furo[3,2-b]pyran-2-one 1,5-anhydro-2-deoxy-3-O-propanoyl-4-O-benzyl-6-O-(tert-butyldimethylsilyl)-D-gluco-hex-1-enitol

下游产品

(S)-5-((S)-2-Benzyloxy-3-oxo-butyl)-3-methyl-5H-furan-2-one (3S,3aS,6S,7aS)-6-Benzyloxy-3-methyl-5-methylene-hexahydro-furo[3,2-b]pyran-2-one (3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one