百科

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

CAS号：78686-74-5

英文名：(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

分子式：C16H22O4

分子量：278.343

合成路线

ethyl 4(R)-<(1R)-3(S),4,8(R)-trimethyl-6-oxo-2,9-dioxabicyclo-<3.3.1>non-4(Z)-en-1-yl>-2-methylpent-2(E)-enoate

ethyl 4(R)-<(1R)-3(S),4,8(R)-trimethyl-6-oxo-2,9-dioxabicyclo-<3.3.1>non-4(Z)-en-1-yl>-2-methylpent-2(E)-enoate

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

上游原料

ethyl 4(R)-<(1R)-3(S),4,8(R)-trimethyl-6-oxo-2,9-dioxabicyclo-<3.3.1>non-4(Z)-en-1-yl>-2-methylpent-2(E)-enoate

下游产品

(2E,4E)-(R)-4-Methyl-6-((1S,3R,4R,5S)-1,4,8-trimethyl-6-oxo-2,9-dioxa-bicyclo[3.3.1]non-7-en-3-yl)-hepta-2,4-dienoic acid methyl ester <1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate