百科

(2E,4E)-(R)-4-Methyl-6-((1S,3R,4R,5S)-1,4,8-trimethyl-6-oxo-2,9-dioxa-bicyclo[3.3.1]non-7-en-3-yl)-hepta-2,4-dienoic acid methyl ester

(2E,4E)-(R)-4-Methyl-6-((1S,3R,4R,5S)-1,4,8-trimethyl-6-oxo-2,9-dioxa-bicyclo[3.3.1]non-7-en-3-yl)-hepta-2,4-dienoic acid methyl ester

CAS号：78699-71-5

英文名：(2E,4E)-(R)-4-Methyl-6-((1S,3R,4R,5S)-1,4,8-trimethyl-6-oxo-2,9-dioxa-bicyclo[3.3.1]non-7-en-3-yl)-hepta-2,4-dienoic acid methyl ester

分子式：C19H26O5

分子量：334.407

合成路线

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal

methyl (triphenylphosphoranylidene)acetate

methyl (triphenylphosphoranylidene)acetate

(2E,4E)-(R)-4-Methyl-6-((1S,3R,4R,5S)-1,4,8-trimethyl-6-oxo-2,9-dioxa-bicyclo[3.3.1]non-7-en-3-yl)-hepta-2,4-dienoic acid methyl ester

(2E,4E)-(R)-4-Methyl-6-((1S,3R,4R,5S)-1,4,8-trimethyl-6-oxo-2,9-dioxa-bicyclo[3.3.1]non-7-en-3-yl)-hepta-2,4-dienoic acid methyl ester

上游原料

(4R,E)-2-methyl-4-((3R,4R)-1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)pent-2-enal methyl (triphenylphosphoranylidene)acetate

下游产品

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate