百科

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

CAS号：794516-06-6

英文名：(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

分子式：C21H32O5Si

分子量：392.561

合成路线

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

methyl 4-O-benzoyl-6-bromo-3-O-[2-{(tert-butyldimethylsilyl)oxy}ethyl]-6-deoxy-α-D-altropyranoside

methyl 4-O-benzoyl-6-bromo-3-O-[2-{(tert-butyldimethylsilyl)oxy}ethyl]-6-deoxy-α-D-altropyranoside

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

(2R,4aR,6S,7S,8S,8aR)-8-(2-Hydroxy-ethoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7S,8S,8aR)-8-(2-Hydroxy-ethoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

methyl 4,6-O-benzylidene-3-O-[2-{(tert-butyldimethylsilyl)oxy}ethyl]-α-D-altropyranoside

methyl 4,6-O-benzylidene-3-O-[2-{(tert-butyldimethylsilyl)oxy}ethyl]-α-D-altropyranoside

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

(3R,4R,5R)-3-benzoyloxy-4-[2-(tert-butyldimethylsilyloxy)ethoxy]-5,6-epoxyhex-1-ene

上游原料

methyl 4-O-benzoyl-6-bromo-3-O-[2-{(tert-butyldimethylsilyl)oxy}ethyl]-6-deoxy-α-D-altropyranoside methyl 4,6-O-benzylidene-3-O-[2-{(tert-butyldimethylsilyl)oxy}ethyl]-α-D-altropyranoside (2R,4aR,6S,7S,8S,8aR)-8-(2-Hydroxy-ethoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

下游产品

(3R,4S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-4-[2-(tert-butyldimethylsilyloxy)ethoxy]oct-1-en-7-yne