百科

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

CAS号：794516-10-2

英文名：(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

分子式：C23H38O6Si

分子量：438.63

合成路线

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

methyl 4-O-benzoyl-6-bromo-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-6-deoxy-α-D-altropyranoside

methyl 4-O-benzoyl-6-bromo-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-6-deoxy-α-D-altropyranoside

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

(2R,4aR,6S,7S,8S,8aR)-8-(4-Hydroxy-butoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7S,8S,8aR)-8-(4-Hydroxy-butoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

methyl 4,6-O-benzylidene-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-α-D-altropyranoside

methyl 4,6-O-benzylidene-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-α-D-altropyranoside

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

(2R,3S,4R)-4-benzoyloxy-3-[4-(tert-butyldimethylsilyloxy)butoxy]hex-5-ene-1,2-diol

上游原料

methyl 4,6-O-benzylidene-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-α-D-altropyranoside methyl 4-O-benzoyl-6-bromo-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-6-deoxy-α-D-altropyranoside methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside (2R,4aR,6S,7S,8S,8aR)-8-(4-Hydroxy-butoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

下游产品

(3R,4S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-4-[4-(tert-butyldimethylsilyloxy)butoxy]oct-1-en-7-yne