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(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

CAS号：797758-74-8

英文名：(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

分子式：C27H44O4Si

分子量：460.721

合成路线

(2E,4R)-2,4-dimethylheptenal

(2E,4R)-2,4-dimethylheptenal

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(R,E)-2,4-dimethylhept-2-en-1-ol

(R,E)-2,4-dimethylhept-2-en-1-ol

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(R,E)-ethyl 2,4-dimethylhept-2-enoate

(R,E)-ethyl 2,4-dimethylhept-2-enoate

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(R)-4-benzyl-3-pentanoyl-2-oxazolidinone

(R)-4-benzyl-3-pentanoyl-2-oxazolidinone

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

(2S,4R,5S,6E,8R)-2-benzoyloxy-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one

上游原料

(R,E)-2,4-dimethylhept-2-en-1-ol (R,E)-ethyl 2,4-dimethylhept-2-enoate (2E,4R)-2,4-dimethylheptenal (R)-4-benzyl-3-pentanoyl-2-oxazolidinone

下游产品

(2Z,4R,5S,6E,8R)-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethyl-2-trimethylsilyloxyundec-2,6-diene (4R,5S,6E,8R)-5-(tert-butyldimethylsilyloxy)-4,6,8-trimethylundec-6-en-3-one (6R,7S,8E,10R)-7-(tert-butyldimethylsilyloxy)-4,6,8,10-tetramethyltridec-8-en-3,5-dione