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(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one
CAS号：804551-99-3
英文名：(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one
分子式：C32H47ClO5Si
分子量：575.251
上游原料
(1S,2R)-1-((E)-5-bromo-pent-3-en-1-ynyl)-2-chloro-cyclopropane
(2R,4S,5S)-4-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-5-methyl-3,7-dioxa-bicyclo[4.1.0]heptane-2-carboxylic acid methyl ester
5-[(4E,6E)-(1S,3R)-9-((1S,2R)-2-chloro-cyclopropyl)-1-methyl-3-trityloxy-nona-4,6-dien-8-ynylsulfanyl]-1-phenyl-1H-tetrazole
(5S,6S)-7-benzyloxy-6-methoxy-5-methyl-hept-3-enoic acid methyl ester
methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate
5-[(5E,7E)-(2R,4R)-10-((1S,2R)-2-Chloro-cyclopropyl)-4-(1-ethoxy-ethoxy)-deca-5,7-dien-9-yne-2-sulfonyl]-1-phenyl-1H-tetrazole
(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester
(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
(E)-5-((1S,2R)-2-chloro-cyclopropyl)-pent-2-en-4-yn-1-ol
(5E,7E)-(2S,4R)-10-((1S,2R)-2-chloro-cyclopropyl)-4-trityloxy-deca-5,7-dien-9-yn-2-ol
(2R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
(5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-5-methyl-4-oxo-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester
5-[(5E,7E)-(2S,4R)-10-((1S,2R)-2-chloro-cyclopropyl)-4-trityloxy-deca-5,7-dien-9-yne-2-sulfonyl]-1-phenyl-1H-tetrazole
[(E)-5-((1S,2R)-2-chloro-cyclopropyl)-pent-2-en-4-ynyl]-phosphonic acid diethyl ester
[(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester
(2R,3S)-4-benzyloxy-3-methoxy-2-methyl-butyraldehyde
(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone
(1R,2S)-1-chloro-2-(2,2-dibromo-vinyl)-cyclopropane
(5S,6S)-7-benzyloxy-6-hydroxy-5-methyl-hept-3-enoic acid methyl ester
(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-hydroxy-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
下游产品
(1S,5R,7E,9R,10R,11R,12R,13S)-5-((1E,3E)-13-(tert-butyl-dimethyl-silanyloxy)-6-((1S,2S)-2-chlorocyclopropyl)-hexa-1,3-dien-5-yn-1-yl)-1-hydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one
(-)-(1S(1R*,5S*,9S*,10S*,11S*,12S*,13R*)7E)-5-[(1E,3E)-6-((1R*,2S*)-2-chlorocyclopropyl)-1,3-hexadien-5-ynyl]-1,13-dihyroxy-9-methoxy-7,10,12-trimethyl-4-15-dioxabicyclo[9.3.1]pentadec-7-en-3-one
