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(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

CAS号：80632-79-7

英文名：(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

分子式：C12H28O2Si

分子量：232.435

合成路线

(2R,3R)-4-benzyloxy-1,2-epoxy-3-methylbutane

(2R,3R)-4-benzyloxy-1,2-epoxy-3-methylbutane

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3R)-4-benzyloxy-1,2-isopropylidenedioxy-3-methylbutane

(2R,3R)-4-benzyloxy-1,2-isopropylidenedioxy-3-methylbutane

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3S)-2-methylpentane-1,3-diol

(2R,3S)-2-methylpentane-1,3-diol

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

((2S,3S)-3-ethyloxiran-2-yl)methyl 4-nitrobenzoate

((2S,3S)-3-ethyloxiran-2-yl)methyl 4-nitrobenzoate

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

(2R,3S)-3-t-butyldimethylsilyloxy-2-methylpentan-1-ol

上游原料

((2S,3S)-3-ethyloxiran-2-yl)methyl 4-nitrobenzoate (2R,3S)-2-methylpentane-1,3-diol (2R,3R)-4-benzyloxy-1,2-epoxy-3-methylbutane (2R,3R)-4-benzyloxy-1,2-isopropylidenedioxy-3-methylbutane

下游产品

(2S,3R,1'S)-epi-stegobinone (2S,3R,1'R,2'R)-stegobiol (2S,3S)-3-tert-butyldimethylsilyloxy-2-methylpentanoic acid (12R,13S)-(+)-12-methyl-10-oxo-13-pentadecanolide (4RS,6R,7S)-4,6-dimethyl-7-hydroxynonan-3-one (2S,3R)-6-[(1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2,3,5-trimethyl-2,3-dihydro-pyran-4-one