百科

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

CAS号：807617-51-2

英文名：(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

分子式：C28H44O5Si

分子量：488.731

合成路线

(1S,4S,6R)-1-{(E)-2-[2-(tert-Butyl-dimethyl-silanyl)-furan-3-yl]-vinyl}-4-(tert-butyl-dimethyl-silanyloxy)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]heptane

(1S,4S,6R)-1-{(E)-2-[2-(tert-Butyl-dimethyl-silanyl)-furan-3-yl]-vinyl}-4-(tert-butyl-dimethyl-silanyloxy)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]heptane

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(-)-[(S)-4-(tert-butyldimethylsilyloxy)-2,6,6-trimethylcyclohex-1-enyl]methanol

(-)-[(S)-4-(tert-butyldimethylsilyloxy)-2,6,6-trimethylcyclohex-1-enyl]methanol

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(2E,4E)-5-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-3-ethoxycarbonylpenta-2,4-dienal

(2E,4E)-5-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-3-ethoxycarbonylpenta-2,4-dienal

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene

(R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

(2E,6Z,8E)-9-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-7-ethoxycarbonyl-3-methylnona-2,6,8-trien-4-yn-1-ol

上游原料

(1S,4S,6R)-1-{(E)-2-[2-(tert-Butyl-dimethyl-silanyl)-furan-3-yl]-vinyl}-4-(tert-butyl-dimethyl-silanyloxy)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]heptane (-)-[(S)-4-(tert-butyldimethylsilyloxy)-2,6,6-trimethylcyclohex-1-enyl]methanol (R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene (2E,4E)-5-[(1'S,2'R,4'S)-4'-tert-butyldimethylsiloxy-1',2'-epoxy-2',6',6'-trimethylcyclohex-1'-yl]-3-ethoxycarbonylpenta-2,4-dienal

下游产品

(5Z)-[(2'E)-4'-hydroxy-2'-methyl-1'-butenylidene]-3-[(1''E)-2''-(1'''S,2'''R,4'''S)-4'''-hydroxy-1''',2'''-epoxy-2''',6''',6'''-trimethylcyclohex-1'''-ylethen-1''-yl]-2(5H)-furanone