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Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

CAS号：81114-59-2

英文名：Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

分子式：C15H24O7

分子量：316.347

合成路线

3-C-hydroxymethyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

3-C-hydroxymethyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

35522-70-4

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

102854-54-6

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

3-deoxy-3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

3-deoxy-3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

3-chloro-3-deoxy-3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

3-chloro-3-deoxy-3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

Acetic acid (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester

上游原料

3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose 3-chloro-3-deoxy-3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 3-deoxy-3-C-formyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose 3-C-hydroxymethyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

下游产品

(7E,9E)-(2S,3aR,5R,6S,11R,12R,16R,17S,17aS)-12-Ethyl-6,16-dihydroxy-2-methoxy-5,9,17-trimethyl-11-trityloxymethyl-2,3,3a,4,5,6,11,12,15,16,17,17a-dodecahydro-1,13-dioxa-cyclopentacyclohexadecen-14-one (E)-(4R,5R,6R)-4,6-Dihydroxy-3-methyl-5-trityloxymethyl-oct-2-enoic acid methyl ester Acetic acid (3aR,5S,6R,6aR)-2,2-dimethyl-5-(toluene-4-sulfonyloxymethyl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-ylmethyl ester ((3aR,5R,6R,6aR)-5-Ethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl)-methanol (E)-(4R,5R)-5-Hydroxy-2-methyl-4-trityloxymethyl-hept-2-enal (3R,4S)-3-Hydroxy-4-[(2S,3R)-3-((4E,6E)-(2S,8R,9S)-9-hydroxy-2,6-dimethyl-3-oxo-8-trityloxymethyl-undeca-4,6-dienyl)-5-methoxy-tetrahydro-furan-2-yl]-pentanoic acid methyl ester (3R,4S,5R)-5-Ethyl-3-hydroxy-4-hydroxymethyl-dihydro-furan-2-one (3R,4S)-4-[(2S,3R,5S)-3-((4E,6E)-(2R,3S,8R,9R)-3,9-Dihydroxy-2,6-dimethyl-8-trityloxymethyl-undeca-4,6-dienyl)-5-methoxy-tetrahydro-furan-2-yl]-3-hydroxy-pentanethioic acid S-pyridin-2-yl ester (3R,4S,5R)-5-Ethyl-3-hydroxy-4-trityloxymethyl-dihydro-furan-2-one