百科

2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

CAS号：81165-10-8

英文名：2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

分子式：C23H23Cl6NO7

分子量：638.149

合成路线

(4R,4aS,7aR,12bS)-4a-hydroxy-3-methyl-2,3,4,4a,5,6-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7(7aH)-one

(4R,4aS,7aR,12bS)-4a-hydroxy-3-methyl-2,3,4,4a,5,6-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7(7aH)-one

2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

4,14-dihydroxy-N-methylmorphinan-6-one

4,14-dihydroxy-N-methylmorphinan-6-one

2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

2,2,2-trichloroethyl (4bR,8aS,9R)-4-methoxy-6-oxo-8a-(((2,2,2-trichloroethoxy)carbonyl)oxy)-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene-11-carboxylate

上游原料

(4R,4aS,7aR,12bS)-4a-hydroxy-3-methyl-2,3,4,4a,5,6-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7(7aH)-one 4,14-dihydroxy-N-methylmorphinan-6-one

下游产品

(-)-14-hydroxy-4-methoxymorphinan-6-one (-)-4-methoxy-14-hydroxy-6-keto-N-cyclopropylcarbonylmorphinan