百科

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

CAS号：815600-28-3

英文名：(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

分子式：C16H35NO5Si

分子量：349.538

合成路线

(R)-1-Methoxy-4-(4-methoxy-benzyloxy)-butan-2-ol

(R)-1-Methoxy-4-(4-methoxy-benzyloxy)-butan-2-ol

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

tert-Butyl-[(R)-3-(4-methoxy-benzyloxy)-1-methoxymethyl-propoxy]-dimethyl-silane

tert-Butyl-[(R)-3-(4-methoxy-benzyloxy)-1-methoxymethyl-propoxy]-dimethyl-silane

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-butan-1-ol

(R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-butan-1-ol

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(R)-4-Methoxymethyl-2-(4-methoxy-phenyl)-[1,3]dioxane

(R)-4-Methoxymethyl-2-(4-methoxy-phenyl)-[1,3]dioxane

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal

(R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

(2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide

上游原料

tert-Butyl-[(R)-3-(4-methoxy-benzyloxy)-1-methoxymethyl-propoxy]-dimethyl-silane (R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-butan-1-ol (R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal (R)-4-Methoxymethyl-2-(4-methoxy-phenyl)-[1,3]dioxane (R)-1-Methoxy-4-(4-methoxy-benzyloxy)-butan-2-ol

下游产品

(2R,3R,4S,5S,6R)-2-[(4R,5S)-5-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4-(tert-butyl-dimethyl-silanyloxy)-6-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran 4-(tert-butyl-dimethyl-silanyloxy)-2-{5-[3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-oct-6-ynyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-6-[2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran 3-(tert-butyl-dimethyl-silanyloxy)-5-(5-{4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl}-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxy-pentan-1-ol 4-(tert-butyl-dimethyl-silanyloxy)-2-{5-[3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-pent-4-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-6-[2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran 3-(tert-butyl-dimethyl-silanyloxy)-1-(5-{4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl}-2,2-dimethyl-[1,3]dioxolan-4-yl)-pent-4-en-2-ol ((4S,5R)-5-{(2R,3R,4S,5S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl}-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde (2S,3R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-3-(4-methoxy-benzyloxy)-2-methyl-hexanal 4-(tert-butyl-dimethyl-silanyloxy)-2-{5-[3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-hept-6-ynyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-6-[2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran 2-((4S,5R)-5-{(2R,3R,4S,5S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-propyl]-2-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl}-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol (2R,3S,4R,5R,7R)-1-[(4R,5S)-5-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-8-methoxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-octan-1-one