百科

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

CAS号：817201-30-2

英文名：(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

分子式：C20H30O4Si

分子量：362.535

合成路线

(1R,6S,7R,8S)-8-Methyl-9-oxa-bicyclo[4.2.1]nona-2,4-diene-7-carboxylic acid

(1R,6S,7R,8S)-8-Methyl-9-oxa-bicyclo[4.2.1]nona-2,4-diene-7-carboxylic acid

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7S,8S)-7-[(1S)-1-(2-furyl)-1-hydroxymethyl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7S,8S)-7-[(1S)-1-(2-furyl)-1-hydroxymethyl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

上游原料

(1R,6S,7R,8S)-8-Methyl-9-oxa-bicyclo[4.2.1]nona-2,4-diene-7-carboxylic acid (1R,6S,7S,8S)-7-[(1S)-1-(2-furyl)-1-hydroxymethyl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

下游产品

(+)-mycoepoxydiene (1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-7-[(2S,3S,6R)-3-acetoxy-6-(tert-butyldimethylsilyloxy)-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-7-[(2S,3S,6R)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene