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(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

CAS号：817201-37-9

英文名：(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

分子式：C16H20O5

分子量：292.327

合成路线

(1R,6S,7R,8S)-7-[(2S,6S)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6S)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S,6S)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S,6S)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S,6R)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S,6R)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S,6R)-3-acetoxy-6-(tert-butyldimethylsilyloxy)-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S,6R)-3-acetoxy-6-(tert-butyldimethylsilyloxy)-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

上游原料

(1R,6S,7R,8S)-7-[(2S,6S)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester (1R,6S,7R,8S)-7-[(2S,6R)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-7-[(2S,3S,6R)-3-acetoxy-6-(tert-butyldimethylsilyloxy)-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-7-[(2S,3S,6S)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-7-[(2S,3S,6R)-6-(tert-butyldimethylsilyloxy)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

下游产品

(+)-mycoepoxydiene