百科

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

CAS号：817201-46-0

英文名：Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

分子式：C22H34O5Si

分子量：406.588

合成路线

(1R,6S,7R,8S)-7-[(2S,6S)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S,6S)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

(1R,6S,7R,8S)-8-Methyl-9-oxa-bicyclo[4.2.1]nona-2,4-diene-7-carboxylic acid

(1R,6S,7R,8S)-8-Methyl-9-oxa-bicyclo[4.2.1]nona-2,4-diene-7-carboxylic acid

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

(1R,6S,7S,8S)-7-[(1S)-1-(2-furyl)-1-hydroxymethyl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7S,8S)-7-[(1S)-1-(2-furyl)-1-hydroxymethyl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

(1R,6S,7R,8S)-7-[(2S)-6-hydroxy-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

(1R,6S,7R,8S)-7-[(2S)-6-hydroxy-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

Acetic acid (2S,3S,6S)-6-(tert-butyl-dimethyl-silanyloxy)-2-((1R,6S,7R,8S)-8-methyl-9-oxa-bicyclo[4.2.1]nona-2,4-dien-7-yl)-3,6-dihydro-2H-pyran-3-yl ester

上游原料

(1R,6S,7R,8S)-7-[(2S,6S)-6-(tert-butyldimethylsilyloxy)-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-7-[(2S)-6-hydroxy-3-oxo-6-hydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene (1R,6S,7R,8S)-8-Methyl-9-oxa-bicyclo[4.2.1]nona-2,4-diene-7-carboxylic acid (1R,6S,7S,8S)-7-[(1S)-1-(2-furyl)-1-hydroxymethyl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene

下游产品

(+)-mycoepoxydiene (1R,6S,7R,8S)-7-[(2S,3S)-3-acetoxy-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]-8-methyl-9-oxabicyclo[4.2.1]nona-2,4-diene