百科

2-((3S,8S,9S,10R,13S,14S,17R)-17-{(S)-1-[(2S,3S)-3-(3-Iodo-2-methyl-propyl)-oxiranyl]-ethyl}-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yloxy)-tetrahydro-pyran

CAS号：82033-32-7

英文名：2-((3S,8S,9S,10R,13S,14S,17R)-17-{(S)-1-[(2S,3S)-3-(3-Iodo-2-methyl-propyl)-oxiranyl]-ethyl}-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yloxy)-tetrahydro-pyran

分子式：C32H51IO3

分子量：610.65

合成路线

3-((2S,3S)-3-{(S)-1-[(3S,8S,9S,10R,13S,14S,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-ethyl}-oxiranyl)-2-methyl-propan-1-ol

82033-30-5

82033-32-7

2-((3S,8S,9S,10R,13S,14S,17R)-17-{(S)-1-[(2S,3S)-3-(3-Iodo-2-methyl-propyl)-oxiranyl]-ethyl}-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yloxy)-tetrahydro-pyran

82033-31-6

Toluene-4-sulfonic acid 3-((2S,3S)-3-{(S)-1-[(3S,8S,9S,10R,13S,14S,17R)-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-ethyl}-oxiranyl)-2-methyl-propyl ester

82033-32-7

76719-23-8

(22E)-cholest-5,22-diene-3β-tetrahydropyranyloxy-26-oic acid ethyl ester

82033-32-7

76726-17-5

(22R)-25,26,27-trisnorcholest-5,23-diene-3β-tetrahydropyranyloxy-22-ol

82033-32-7

76719-25-0

cholest-5-ene-3β-hydroxy-22-iodo-26,23-lactone

82033-32-7

76719-27-2

(S)-5-{(1R,2S)-2-[(3S,8S,9S,10R,13S,14S,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-1-iodo-propyl}-3-methyl-dihydro-furan-2-one

82033-32-7

82033-29-2

cholest-5-en-22,23-epoxy-3β-tetrahydropyranyloxy-26-oic acid methyl ester

82033-32-7

76719-24-9

(E)-(R)-6-((3S,8S,9S,10R,13R,14S,17R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-methyl-hept-4-enoic acid

82033-32-7

上游原料

3-((2S,3S)-3-{(S)-1-[(3S,8S,9S,10R,13S,14S,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-ethyl}-oxiranyl)-2-methyl-propan-1-ol Toluene-4-sulfonic acid 3-((2S,3S)-3-{(S)-1-[(3S,8S,9S,10R,13S,14S,17R)-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-ethyl}-oxiranyl)-2-methyl-propyl ester (E)-(R)-6-((3S,8S,9S,10R,13R,14S,17R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-methyl-hept-4-enoic acid (22E)-cholest-5,22-diene-3β-tetrahydropyranyloxy-26-oic acid ethyl ester (S)-5-{(1R,2S)-2-[(3S,8S,9S,10R,13S,14S,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-1-iodo-propyl}-3-methyl-dihydro-furan-2-one (22R)-25,26,27-trisnorcholest-5,23-diene-3β-tetrahydropyranyloxy-22-ol cholest-5-ene-3β-hydroxy-22-iodo-26,23-lactone cholest-5-en-22,23-epoxy-3β-tetrahydropyranyloxy-26-oic acid methyl ester

下游产品

(2S,3R)-2-[(3S,8S,9S,10R,13S,14S,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl]-6-methyl-heptan-3-ol (20R,22S)-3β,22-Dihydroxycholest-5-en (2R,4S)-2-((3S,10R,13R,17R)-10,13-dimethyl-3-((tetrahydro-2H-pyran-2-yl)oxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-6-methylheptan-4-ol cholest-5-ene-3β-tetrahydropyranyloxy-22,23-epoxide