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(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

CAS号：823788-02-9

英文名：(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

分子式：C17H35NOSi

分子量：297.551

合成路线

N-(2-Iodo-allyl)-4-methyl-N-((1R,5S)-5-methyl-4-oxo-cyclopent-2-enylmethyl)-benzenesulfonamide

N-(2-Iodo-allyl)-4-methyl-N-((1R,5S)-5-methyl-4-oxo-cyclopent-2-enylmethyl)-benzenesulfonamide

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4aR,6S,7S,7aR)-6-{[tert-butyl(dimethyl)silyl]oxy}-7-methyl-4-methylene-octahydro-1H-cyclopenta[c]pyridine

(4aR,6S,7S,7aR)-6-{[tert-butyl(dimethyl)silyl]oxy}-7-methyl-4-methylene-octahydro-1H-cyclopenta[c]pyridine

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4aR,7S,7aS)-7-methyl-4-methylene-2-[(4-methylphenyl)sulfonyl]octahydro-6H-cyclopenta[c]pyridin-6-one

(4aR,7S,7aS)-7-methyl-4-methylene-2-[(4-methylphenyl)sulfonyl]octahydro-6H-cyclopenta[c]pyridin-6-one

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-6-(tert-butyldimethylsilyloxy)-2,4,7-trimethyl-octahydrocyclopenta[c]pyridin-1-one

(4R,4aS,6S,7S,7aR)-6-(tert-butyldimethylsilyloxy)-2,4,7-trimethyl-octahydrocyclopenta[c]pyridin-1-one

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4aR,6S,7S,7aR)-6-{[tert-butyl(dimethyl)silyl]oxy}-7-methyl-4-methylene-2-[(4-methylphenyl)sulfonyl]octahydro-1H-cyclopenta[c]pyridine

(4aR,6S,7S,7aR)-6-{[tert-butyl(dimethyl)silyl]oxy}-7-methyl-4-methylene-2-[(4-methylphenyl)sulfonyl]octahydro-1H-cyclopenta[c]pyridine

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

(4R,4aS,6S,7S,7aR)-2,4,7-trimethyl-octahydro-1H-cyclopenta[c]pyridin-6-yl tert-butyl(dimethyl)silyl ether

上游原料

N-(2-Iodo-allyl)-4-methyl-N-((1R,5S)-5-methyl-4-oxo-cyclopent-2-enylmethyl)-benzenesulfonamide (4aR,6S,7S,7aR)-6-{[tert-butyl(dimethyl)silyl]oxy}-7-methyl-4-methylene-octahydro-1H-cyclopenta[c]pyridine (4aR,7S,7aS)-7-methyl-4-methylene-2-[(4-methylphenyl)sulfonyl]octahydro-6H-cyclopenta[c]pyridin-6-one (4R,4aS,6S,7S,7aR)-6-(tert-butyldimethylsilyloxy)-2,4,7-trimethyl-octahydrocyclopenta[c]pyridin-1-one (4aR,6S,7S,7aR)-6-{[tert-butyl(dimethyl)silyl]oxy}-7-methyl-4-methylene-2-[(4-methylphenyl)sulfonyl]octahydro-1H-cyclopenta[c]pyridine

下游产品

(4R,4aS,6R,7S,7aR)-2,4,7-trimethyloctahydro-1H-cyclopenta[c]pyridin-6-yl 4-nitrobenzoate bis[(4R,4aS,6R,7S,7aR)-2,4,7-trimethyloctahydro-1H-cyclopenta[c]pyridin-6-yl] 2,4-bis(3-methoxy-4-{[(4-methylphenyl)sulfonyl]oxy}phenyl)cyclobutane-1,3-dicarboxylate