百科

4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

CAS号：82511-03-3

英文名：4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

分子式：C21H38O2Si

分子量：350.611

合成路线

4-(phenylthio)-7,7-dimethyl-cis-bicyclo<3.3.0>oct-3-en-2-one

4-(phenylthio)-7,7-dimethyl-cis-bicyclo<3.3.0>oct-3-en-2-one

4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

methyl 4,4-dimethylcyclopent-1-enecarboxylate

methyl 4,4-dimethylcyclopent-1-enecarboxylate

4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

4,7,7-trimethyl-4-<1-<2-<(tert-butyldimethylsilyl)oxy>ethyl>vinyl>-cis-bicyclo<3.3.0>octan-2-one

上游原料

methyl 4,4-dimethylcyclopent-1-enecarboxylate 4-(phenylthio)-7,7-dimethyl-cis-bicyclo<3.3.0>oct-3-en-2-one

下游产品

(3R,3aR,6aS)-3-(3-Hydroxy-1-methylene-propyl)-3,5,5-trimethyl-hexahydro-pentalen-1-one