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{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

CAS号：827603-05-4

英文名：{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

分子式：C24H41BrO3Si

分子量：485.57

合成路线

(2R,3S,4S)-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal

(2R,3S,4S)-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

(2S,3R,4S)-5-[(4-methoxybenzyl)oxy]-2,4-dimethylpentane-1,3-diol

(2S,3R,4S)-5-[(4-methoxybenzyl)oxy]-2,4-dimethylpentane-1,3-diol

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

(2S,4S,5R)-6-(tert-butyldimethylsilyloxy)-5-hydroxy-1-(4-methoxybenzyloxy)-2,4-dimethylhexan-3-one

(2S,4S,5R)-6-(tert-butyldimethylsilyloxy)-5-hydroxy-1-(4-methoxybenzyloxy)-2,4-dimethylhexan-3-one

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

(2R,3R,4S,5S)-1-(tert-butyldimethylsilyloxy)-6-(4-methoxybenzyloxy)-3,5-dimethyl-hexane-2,4-diol

(2R,3R,4S,5S)-1-(tert-butyldimethylsilyloxy)-6-(4-methoxybenzyloxy)-3,5-dimethyl-hexane-2,4-diol

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

(2S,4S)-1-hydroxy-5-(p-methoxybenzyloxy)-2,4-dimethylpentan-3-one

(2S,4S)-1-hydroxy-5-(p-methoxybenzyloxy)-2,4-dimethylpentan-3-one

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

methyl(2Z,4S,5R,6S)-5-hydroxy-7-(p-methoxybenzyloxy)-2,4,6-trimethylhept-2-enoate

methyl(2Z,4S,5R,6S)-5-hydroxy-7-(p-methoxybenzyloxy)-2,4,6-trimethylhept-2-enoate

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

methyl (2Z,4S,5R,6S)-5-(t-butyldimethylsilyloxy)-7-(p-methoxybenzyloxy)-2,4,6-trimethylhept-2-enoate

methyl (2Z,4S,5R,6S)-5-(t-butyldimethylsilyloxy)-7-(p-methoxybenzyloxy)-2,4,6-trimethylhept-2-enoate

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

{(Z)-(1R,2S)-5-Bromo-1-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2,4-dimethyl-pent-3-enyloxy}-tert-butyl-dimethyl-silane

上游原料

methyl(2Z,4S,5R,6S)-5-hydroxy-7-(p-methoxybenzyloxy)-2,4,6-trimethylhept-2-enoate (2R,3S,4S)-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal methyl (2Z,4S,5R,6S)-5-(t-butyldimethylsilyloxy)-7-(p-methoxybenzyloxy)-2,4,6-trimethylhept-2-enoate (2S,3R,4S)-5-[(4-methoxybenzyl)oxy]-2,4-dimethylpentane-1,3-diol (2S,4S,5R)-6-(tert-butyldimethylsilyloxy)-5-hydroxy-1-(4-methoxybenzyloxy)-2,4-dimethylhexan-3-one (2S,4S)-1-hydroxy-5-(p-methoxybenzyloxy)-2,4-dimethylpentan-3-one (2R,3R,4S,5S)-1-(tert-butyldimethylsilyloxy)-6-(4-methoxybenzyloxy)-3,5-dimethyl-hexane-2,4-diol

下游产品

(Z)-(6S,7R,8S)-7-(tert-butyldimethylsilanyloxy)-9-(4-methoxybenzyloxy)-4,6,8-trimethylnon-4-enoic acid 2,6-dimethylphenyl ester