百科

N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

CAS号：82801-40-9

英文名：N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

分子式：C21H37NO6SSi

分子量：459.672

合成路线

tert-Butyl-((2R,3R,6S)-2-methoxy-4,6-dimethyl-3,6-dihydro-2H-pyran-3-yloxy)-dimethyl-silane

tert-Butyl-((2R,3R,6S)-2-methoxy-4,6-dimethyl-3,6-dihydro-2H-pyran-3-yloxy)-dimethyl-silane

(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3,4-diol

(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3,4-diol

N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

tert-Butyl-((2S,3S,4S,5R,6R)-2-methoxy-4,6-dimethyl-5-phenylselanyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane

tert-Butyl-((2S,3S,4S,5R,6R)-2-methoxy-4,6-dimethyl-5-phenylselanyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane

N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

N-[(2R,3R,4R,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl]-4-methyl-benzenesulfonamide

上游原料

tert-Butyl-((2S,3S,4S,5R,6R)-2-methoxy-4,6-dimethyl-5-phenylselanyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane tert-Butyl-((2R,3R,6S)-2-methoxy-4,6-dimethyl-3,6-dihydro-2H-pyran-3-yloxy)-dimethyl-silane

下游产品

N-((2R,3R,4S,5S,6S)-4,5-Dihydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl)-4,N-dimethyl-benzenesulfonamide Methyl-4,6-didesoxy-3-C-methyl-N-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid